Synthesis and Applications of Onium Salts for Photopolymerization Reactions
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
The synthesis and characterization of phosphonium and arsonium salts having anthraquinone and anthracene moiety was carried out by reacting equimolar amounts of halomethyl anthracene or anthraquinone with triphenylphosphine or triphenyl arsine in toluene solvent. The halide counter (Cl or Br) ion was exchanged with hexafluoro antimonate (SbF6-) which proved to be a useful photoinitiator for polymerizing cyclohexene oxide, styrene, p-methyl styrene, and N-vinylcarbazole. The experimental results demonstrate the effects of salt, monomer structures, and the photolysis time on the rate of polymerization and the number average molecular weight of the obtained polymer. These salts are easy to handle, nonhygroscopic under laboratory conditions, and they have good solubility in halogenated solvents such as dichloromethane and chloroform.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.002 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it