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Record W4400611409 · doi:10.48550/arxiv.2407.08075

Temperature-Dependent Photoluminescence of PEDOT:PSS for use as Transparent Electrodes in the DarkSide-20k Time Projection Chamber

2024· preprint· en· W4400611409 on OpenAlexfundno aff
N. Swidinsky, E. Ellingwood, J. Hucker, Peter Skensved, Philippe Di Stefano, Jeffery Mason, M. G. Boulay, Ashlea Kemp, Frederick Schuckman, Yi Wang

Bibliographic record

VenuearXiv (Cornell University) · 2024
Typepreprint
Languageen
FieldMaterials Science
TopicElectron and X-Ray Spectroscopy Techniques
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of CanadaQueen's University
KeywordsPEDOT:PSSTime projection chamberPhotoluminescenceMaterials scienceElectrodeProjection (relational algebra)OptoelectronicsOpticsComposite materialPolymerComputer sciencePhysicsDetector

Abstract

fetched live from OpenAlex

Dual-phase time-projection chambers (TPCs) filled with noble elements are used for particle detection, with many focusing on rare-event searches. These detectors measure two signals: one from scintillation light, and another from drifting ionized electrons. The DarkSide-20k design uses a transparent vessel with external photodetectors. Electrodes, used to drift the electrons, are located between the active medium and the photodetectors, requiring them to be transparent to allow scintillation light to transmit through them. The transparent electrode coating for DarkSide-20k is poly(3,4-ethylenedioxythiophene) poly(styrene sulfonate) (PEDOT:PSS) or Clevios. For rare-event search detectors, the fluorescence of materials that are between the active volume and the photodetectors may lead to backgrounds in the data. Since Clevios is a new material for TPC electrodes, its fluorescent properties need to be characterized to understand their potential impact on backgrounds. Previous studies have indicated that Clevios can fluoresce, with maximal fluorescence produced using UV-excitation. Our study analyzes the fluorescence of Clevios, under UV-excitation, using both time-resolved and spectral techniques between 4 K and 300 K. We find that the fluorescence of Clevios is negligible when compared to the fluorescence of common fluorescent materials used in TPCs, such as 1,1,4,4-tetraphenyl-1,3-butadiene (TPB).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.050
GPT teacher head0.238
Teacher spread0.188 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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