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Record W4401296720 · doi:10.1016/j.heliyon.2024.e35739

Effects of Ti substitution by Zr, on the microstructure and hydrogen storage properties OF Ti2-xZrxCrV (x = 0.5, 1, 1.5, 2) alloys

2024· article· en· W4401296720 on OpenAlexaff
Daniela Bellon Monsalve, Elena Ulate-Kolitsky, A Martínez-Amariz, Jacques Huot

Bibliographic record

VenueHeliyon · 2024
Typearticle
Languageen
FieldMaterials Science
TopicHydrogen Storage and Materials
Canadian institutionsUniversité du Québec à Trois-Rivières
FundersUniversité Paris-Saclay
KeywordsMicrostructureSubstitution (logic)Hydrogen storageMaterials scienceCrystal structureHydrogenMetallurgyCrystallographyChemical engineeringChemistryAlloyOrganic chemistry

Abstract

fetched live from OpenAlex

The effect of the substitution of Ti by Zr on the crystal structure, microstructure, and first hydrogenation behavior of Ti 2-x Zr x CrV where X = 0.5, 1.0, 1.5, and 2.0 have been investigated. The samples were synthesized by arc-melting and characterized by X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy. The hydrogenation capacity was measured using a home-made Sieverts apparatus. Pure-Ti 2 CrV crystallizes in a body-centered cubic structure (BCC). Substitution of Ti by Zr leads to the appearance of a secondary phase, namely a C15 Laves phase for the Ti-containing samples, and C15 Laves phase plus a Zr-rich phase for the X = 2.0 sample. The substitution of Ti by Zr increased the lattice parameters in both phases for all samples. Increasing Zr content made the first hydrogenation faster but reduced the hydrogen capacity.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.021
Threshold uncertainty score0.363

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.211
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2024
Admission routes1
Has abstractyes

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