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Record W4402430360 · doi:10.1021/acsomega.4c02995

The Early Cretaceous Sembar Formation, Southern Indus Basin, Pakistan: Biomarkers and Trace Element Distributions to Investigate the Sedimentary Palaeoenvironment and Organic Matter Input

2024· article· en· W4402430360 on OpenAlexaff
Waqas Naseem, Irfan Ullah Jan, Khairul Azlan Mustahpa, Mohammed Hail Hakimi, Shabeer Ahmed, Ali Y. Kahal

Bibliographic record

VenueACS Omega · 2024
Typearticle
Languageen
FieldEngineering
TopicHydrocarbon exploration and reservoir analysis
Canadian institutionsGeoscience BC
FundersHigher Education Commision, PakistanKing Saud University
KeywordsCretaceousGeologyIndusStructural basinSedimentary rockPaleontologyOrganic matterTrace fossilTrace elementSedimentary organic matterGeochemistryEcology

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide The Early Cretaceous clay-rich facies of the Sembar Formation represent the most significantly occurring organic-rich sediments in the Southern Indus Basin of Pakistan. In this study, detailed geochemical research of total organic carbon, biomarker, mineralogy and trace elemental compositions, together with kerogen microscopic analysis, were carried out and used to understand the organic matter input and the dispositional environmental setting of the organic-rich Sembar shale. The Sembar shales have high organic matter, as indicated by the total organic carbon (TOC) content of up to 2.31 wt %. These shales contain a high abundance of liptinites (i.e., alginite and bituminite), with significant reactive vitrinite maceral, reflecting a mixed-organic matter with a high contribution of marine-derived input. The biomarker distributions evidence the finding of mainly marine organic matter. The biomarker characteristics such as Pr/Ph, Pr/n-C 17, Ph/n-C 18, and tricyclic terpane ratios together with C 27 –C 29 regular sterane distributions show that the source of organic matter was primarily marine-derived from mainly phytoplankton algae, along with amounts of land plant input, and accumulated under a low oxygenated environment. The Sembar shale facies are characterized by high Mo trace element content and high V/Ni and Mo/TOC ratios, suggesting anoxic and nonsulfidic environmental conditions during time deposition. The geochemical proxies such as the Sr/Ba ratio and gammacerane/C 30 hopane (G/C 30 ) index suggest that the Sembar shale facies were deposited in a relatively low moderate stratified water column. The higher gallium (Ga) than rubidium (Rb), with high Ga/Rb ratios, indicates a high abundance of the kaolinite mineral, thereby deducing the subaerial weathering during the warm and humid climatic conditions. In this case, these warm and humid climatic conditions cause an influx of masses of nutrients, which could be attributed to increasing marine primary bioproductivity. These large masses of nutrients into the photic zone are also attributed to the presence of the upwelling system during the deposition time. Therefore, such conditions of bioproductivity and preservation of organic matter (OM) resulted in the accumulation of organic carbon in the shale facies of the Early Cretaceous Sembar Formation.

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How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.390
Threshold uncertainty score0.359

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.201
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2024
Admission routes1
Has abstractyes

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