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Record W4402469789 · doi:10.1016/j.cep.2024.109995

Intensified processes for CO2 capture and valorization by catalytic conversion

2024· article· en· W4402469789 on OpenAlexaff
Maria C. Iliuta

Bibliographic record

VenueChemical Engineering and Processing - Process Intensification · 2024
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysts for Methane Reforming
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsCatalysisEnvironmental scienceProcess engineeringWaste managementChemistryEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

Energy and environmental issues are today's major concerns. To solve huge energy needs, the increasing use of fossil fuels leads to significant amounts of CO 2 emissions, which have major negative effects on the environment. An urgent reduction in CO 2 emissions is therefore an absolute priority to minimize the actual global warming. Carbon capture & utilization (CCU) has been introduced as a sustainable avenue. Viewing CO 2 as a resource (renewable feedstock) rather than a waste, its conversion into different value-added products offers an attractive and efficient alternative to CO 2 storage via chemical recycling. However, CO 2 is a very stable molecule whose conversion is a very difficult and complex task. On the other hand, from a sustainable development perspective, CO 2 conversion by catalytic hydrogenation reactions requires hydrogen derived from renewable sources. Because of numerous benefits, our group has been focussing high attention to the application of different process intensification tools to proposed technologies for CO 2 capture in gas/liquid contactors (including membrane separation and enzymatic processes), highly pure hydrogen production with in-situ CO 2 capture, and CO 2 conversion by catalytic hydrogenation, which will be reviewed in the present paper.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.241
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2024
Admission routes1
Has abstractyes

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