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Record W4402518461 · doi:10.26434/chemrxiv-2024-c9w7l

Fabrication of superhydrophilic membranes for oil-water separation: A life cycle assessment study

2024· preprint· en· W4402518461 on OpenAlexaff
Dixit V. Bhalani, Yi Yang, Suresh K. Jewrajka, Junjie Shen

Bibliographic record

VenueChemRxiv · 2024
Typepreprint
Languageen
FieldEnvironmental Science
TopicMembrane Separation Technologies
Canadian institutionsQueen's University
FundersRoyal Academy of Engineering
KeywordsSuperhydrophilicityFabricationMembraneSeparation (statistics)Materials sciencePetroleum engineeringProcess engineeringChemical engineeringEnvironmental scienceEngineeringComputer scienceChemistryWetting

Abstract

fetched live from OpenAlex

Membrane-based technologies are widely used in oily wastewater treatment. This study selects two superhydrophilic ultrafiltration (UF) membranes (denoted M1 and M2) for oil-in-water emulsion separation and evaluates the environmental impact of membrane fabrication using life cycle assessment (LCA). Although the two membranes have similar separation performance, M1 exhibits ~40% lower environmental impacts than M2 in almost every category owing to its fewer modification steps, lower electricity use, and less solvent consumption. Electricity consumption, reactive-copolymer synthesis, and toxic-solvent use are identified as environmental hotspots in membrane fabrication. A sensitivity analysis of different energy sources reveals that coal-based electricity has the greatest environmental impact, while photovoltaic energy reduces the impact by up to 71%. Considering solvents, dimethylformamide (DMF) shows a slightly lower environmental impact than N-methyl-2-pyrrolidone (NMP).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.144
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.028
GPT teacher head0.317
Teacher spread0.289 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2024
Admission routes1
Has abstractyes

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