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Synthesis and Characterization of Dy<sub>2</sub>O<sub>3</sub>@TiO<sub>2</sub> Nanocomposites for Enhanced Photocatalytic and Electrocatalytic Applications

2024· article· en· W4402572670 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueACS Engineering Au · 2024
Typearticle
Languageen
FieldEnergy
TopicAdvanced Photocatalysis Techniques
Canadian institutionsUniversité du Québec à Chicoutimi
FundersKing Saud University
KeywordsPhotocatalysisCharacterization (materials science)NanocompositeMaterials scienceChemical engineeringNanotechnologyCatalysisChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Industrial wastewater pollution is a crucial global issue due to the increasing need for clean water. Traditional photocatalytic methods for eliminating harmful dyes are often ineffective and are environmentally damaging. This study introduces a new, efficient photocatalyst combining Dy 2 O 3 with TiO 2 using a single-step hydrothermal approach. Dy 2 O 3 @TiO 2 nanostructures were synthesized and characterized by using XRD, SEM, EDS, TEM, BET, and UV–visible spectroscopy. Dy 2 O 3 was evenly distributed on TiO 2, preventing clumping and resulting in a larger surface area with more active sites. UV irradiation (365 nm) replaced the traditional thermal energy for photocatalytic dye breakdown, leveraging the varying conductivity of the Dy 2 O 3 @TiO 2 nanocomposites. Incorporating Dy 2 O 3 decreased band gaps, enhancing redox reactions and expanding the range of degradable contaminants. For Rhodamine B dye degradation, the Dy 2 O 3 @TiO 2 composite demonstrated significantly higher degradation rates than Dy 2 O 3 or TiO 2 alone at reaction parameters such as neutral pH (pH 7) and catalyst concentration (2 g L –1 ). The hybrid material also demonstrated improved electrocatalytic activity in oxygen reduction reactions (ORRs) under alkaline conditions with an initial potential of 0.88 V and a Tafel slope of 73 mV dec –1 . The enhanced catalytic activity and durability are attributed to the synergistic interaction between Dy 2 O 3 and TiO 2 . This novel photocatalyst offers a sustainable alternative for treating industrial effluents while reducing the environmental impact.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.139
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.213
Teacher spread0.208 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it