Flash Joule Heating Synthesis of Layer-Stacked Vanadium Oxide/Graphene Hybrids within Seconds for High-Performance Aqueous Zinc-Ion Batteries
Bibliographic record
Abstract
Vanadium oxides have been regarded as highly promising cathodes for aqueous zinc-ion batteries (ZIBs). However, obtaining high-performance vanadium oxide-based cathodes suitable for industrial application remains a significant challenge due to the need for cost-effective, straightforward, and efficient preparation methods. Herein, we present a facile and rapid synthesis of a composite cathode, consisting of layer-stacked VO 2 /V 2 O 5 and graphene-like carbon nanosheets, in just 2.5 s by treating the commercial V 2 O 5 powder via a flash Joule heating strategy. When employed as the cathode for ZIBs, the resulting composite delivers a comparable rate capacity of 459 mA h g –1 at 0.2 A g –1 and remarkable cycle stabilities of 355.5 mA h g –1 after 2500 cycles at 1.0 A g –1 and 169.5 mA h g –1 after 10,000 cycles at 10 A g –1, respectively. Further electrochemical analysis reveals that the impressive performance is attributed to the accelerated charge transfer and the alleviated structure degradation, facilitated by the abundant sites and a built-in electric field of the layer-stacked VO 2 /V 2 O 5 heterostructure, as well as the excellent conductivity of graphene-like carbon nanosheets. This work introduces a unique approach for ultrafast and low-cost fabrication of high-performance vanadium oxide-based composite cathodes toward efficient ZIBs.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".