Preparation of novel fluorinated highly branched (<scp>A<sub>3</sub></scp> + <scp>B<sub>3</sub></scp>)‐type hyperbranched poly(amide‐imides) for electrochromism and iodine adsorption
Why this work is in the frame
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Bibliographic record
Abstract
Abstract In this study, a series of (A 3 + B 3 )‐type fluorinated hyperbranched poly(amide‐imides) were successfully synthesized with carbazole and fluorene units as end‐capping moieties. All synthesized end‐capping hyperbranched PAIs showed over 70% branching as determined by 1 H NMR, demonstrating good solubility and thermal stability ( T g s : 242–263°C, T 10% : 576–629°C). The HOMO and LUMO energy levels of hyperbranched PAI films were measured at 4.65–4.73 and 1.51–1.66 eV, respectively, suggesting favorable reoxidation and reduction characteristics. PAI‐2 demonstrates a 46.6% transmittance variation ( ∆T , 418 nm), along with a coloring/bleaching process time of 2.3 s/1.6 s, a coloring efficiency (CE) of 310 cm 2 /C, and exceptional redox stability over 100 cycles. Furthermore, the synthesized PAIs containing electron‐withdrawing groups exhibited a high iodine adsorption capacity as determined by iodine adsorption tests (PAI‐1: 534 mg/g, PAI‐2: 579 mg/g, PAI‐3: 490 mg/g).
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.003 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.001 | 0.002 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.001 | 0.002 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it