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Record W4402664842 · doi:10.1002/anie.202415032

Honeycomb‐Structured IrO <sub>x</sub> Foam Platelets as the Building Block of Anode Catalyst Layer in PEM Water Electrolyzer

2024· article· en· W4402664842 on OpenAlexafffund
Zhoubing Xie, Hui Chen, Xiyang Wang, Yimin A. Wu, Zizhun Wang, Subhajit Jana, Yongcun Zou, Xiao Zhao, Xiao Liang, Xiaoxin Zou

Bibliographic record

VenueAngewandte Chemie International Edition · 2024
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsUniversity of Waterloo
FundersFundamental Research Funds for the Central UniversitiesHigher Education Discipline Innovation ProjectPeople's Government of Jilin ProvinceChina Postdoctoral Science FoundationEducation Department of Jilin ProvinceKey Technologies Research and Development ProgramNational Natural Science Foundation of ChinaCanadian Light Source
KeywordsMaterials scienceProton exchange membrane fuel cellAnodeCatalysisElectrolysisChemical engineeringHoneycombOxygen evolutionLayer (electronics)Membrane electrode assemblyIridiumComposite materialElectrodeElectrochemistryChemistryElectrolyte

Abstract

fetched live from OpenAlex

Abstract Achieving robust long‐term durability with high catalytic activity at low iridium loading remains one of great challenges for proton exchange membrane water electrolyzer (PEMWE). Herein, we report the low‐temperature synthesis of iridium oxide foam platelets comprising edge‐sharing IrO 6 octahedral honeycomb framework, and demonstrate the structural advantages of this material for multilevel tuning of anodic catalyst layer across atomic‐to‐microscopic scales for PEMWE. The integration of IrO 6 octahedral honeycomb framework, foam‐like texture and platelet morphology into a single material system assures the generation and exposure of highly active and stable iridium catalytic sites for the oxygen evolution reaction (OER), while facilitating the reduction of both mass transport loss and electronic resistance of catalyst layer. As a proof of concept, the membrane electrode assembly in single‐cell PEMWE based on honeycomb‐structured IrO x foam platelets, with a low iridium loading (~0.3 mg Ir /cm 2 ), is demonstrated to exhibit high catalytic activity at ampere‐level current densities and to remain stable for more than 2000 hours.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.013
Threshold uncertainty score0.756

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.230
Teacher spread0.223 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations60
Published2024
Admission routes2
Has abstractyes

Explore more

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