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Record W4402675246 · doi:10.1016/j.cej.2024.155929

Simulation and experimental demonstration of helium purification from He/N2 mixtures by pressure swing adsorption

2024· article· en· W4402675246 on OpenAlexafffund
Raviraju Vysyaraju, James A. Sawada, Libardo Estupiñan Pérez, Arvind Rajendran

Bibliographic record

VenueChemical Engineering Journal · 2024
Typearticle
Languageen
FieldEngineering
TopicSuperconducting Materials and Applications
Canadian institutionsVanguard CollegeUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of CanadaAlliance de recherche numérique du CanadaAlberta Innovates
KeywordsPressure swing adsorptionHeliumSwingAdsorptionChemistryMaterials scienceChromatographyChemical engineeringEngineeringOrganic chemistryMechanical engineering

Abstract

fetched live from OpenAlex

Terrestrial helium is an indispensable non-renewable resource used in medicine, space, electronics, and nuclear research. This paper reports a high-pressure five-step pressure swing adsorption (PSA) cycle using Zeolite 5A for purification of He from dilute He/N 2 mixtures. A Dual-Site Langmuir (DSL) model fitted both the low-pressure N 2 and high-pressure N 2 isotherm data. Dynamic column breakthrough (DCB) experiments were used to confirm volumetric equilibrium loadings. The DCB model predicted the experimental breakthrough curves for a wide range of feed compositions (100% N 2 , 74.5% N 2 , and 51.5% N 2 ) and feed pressures (1 bar and 11.2 bar). A large experimental campaign studied the impact of various operating conditions on the He purity and recovery achievable from the PSA process. The study showed that a single-stage PSA experiment could enrich He up to 13% purity with greater than 90% recovery from a feed containing 1% He. Helium purity of 95% and a recovery of 90% can be achieved from a feed containing 10% He. All trends were predicted well by numerical simulations. A multi-objective optimization was performed to maximize helium purity and recovery for various He feed compositions. The study also showed that points from the Pareto curve can be realized experimentally.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.015

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.229
Teacher spread0.219 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2024
Admission routes2
Has abstractyes

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