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Record W4402700414 · doi:10.15372/aoo20231105

CHLORINE OXIDE AS AN INDICATOR OF OZONE DESTRUCTION IN THE WINTER-SPRING ARCTIC STRATOSPHERE BASED ON AURA MLS OBSERVATIONS

2023· article· ru· W4402700414 on OpenAlexaboutno aff
O. Bazhenov

Bibliographic record

VenueOptika atmosfery i okeana · 2023
Typearticle
Languageru
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsnot available
Fundersnot available
KeywordsStratosphereOzone depletionOzoneSpring (device)ArcticOzone layerEnvironmental scienceChlorineThe arcticAtmospheric sciencesEnvironmental chemistryChemistryOceanographyMeteorologyGeologyGeography

Abstract

fetched live from OpenAlex

В настоящее время все большее беспокойство вызывает поведение озона в Арктике, аномалии которого происходят в среднем раз в пять лет. Последнее, рекордное понижение уровня озона в стратосфере Арктики зафиксировано в марте-апреле 2020 г. В феврале 2022 г. разрушение озона развивалось по сценарию, близкому к озоновой аномалии 2020 г. Как и в 2020 г., в 2022 г. после возвращения солнечного освещения в Арктику значительно выросло отношение смеси ClO, которое можно рассматривать в качестве надежного показателя разрушения озона. Однако дальнейшее разрушение было остановлено в результате внезапного мажорного стратосферного потепления 20 марта. В работе используются данные измерений общего содержания озона (ОСО) за 2003-2022 гг. из сервиса TEMIS, а также профили температуры воздуха и отношений смеси озона за 2005-2022 гг. и оксида хлора за 2020-2022 гг. из измерений Aura MLS. Рассмотрены следующие пункты: Эврика (Канада), Ню-Олесунн (Норвегия), Резольют (Канада), Туле (Гренландия). Выявлена зависимость между содержанием озона и оксида хлора. Высокая корреляция колебаний рассматриваемых параметров на приблизительно одинаковых высотах регистрации, а также значений общего содержания O3 и ClO говорит об их тесной взаимосвязи. Результаты позволяют использовать концентрацию и общее содержание ClO в качестве индикаторов разрушения озона в стратосфере Арктики. Behavior of ozone in the Arctic is of major concern. Ozone anomalies occur every five years on the average. The last, record strong decrease of the ozone level in the stratosphere of the Arctic took place in March-April 2020. In February 2022, ozone destruction developed by the scenario very similar to the anomaly of 2020. Like in 2020, the ClO mixing ratio, which can be considered a reliable indicator of ozone destruction, strongly increased after the end of the polar night in Arctic latitudes in 2022, but the subsequent ozone depletion process was halted by a sudden major stratospheric warming on March 20, 2022. In this work, we analyze ozone destruction in 2020-2022 based on measurements of the total ozone content over 2003-2022 from the TEMIS service, profiles of the air temperature and ozone mixing ratio for 2005-2022 and of ClO mixing ratio for 2020-2022 from Aura MLS observations. The following sites are considered: Eureka, Canada; Ny-Ålesund, Norway; Thule, Greenland; and Resolute, Canada. A relationship is revealed between ozone and chlorine oxide contents. High coefficients of correlations between oscillations of the above parameters at close altitudes of their recording, as well as between the total O3 and ClO contents calculated from their profiles, indicates their close interrelation. Hence, the ClO concentration and total content can be used as indicators of ozone destruction in the Arctic stratosphere.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.086
Threshold uncertainty score0.171

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.032
GPT teacher head0.249
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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