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Record W4402896227 · doi:10.5539/ijc.v16n2p75

Calculations Reconsidered: From Mass Percentages of Elements to Empirical Formula and From Empirical Formula to Theoretical Biomethane Potential

2024· article· en· W4402896227 on OpenAlexvenueno aff
Pong Kau Yuen, Cheng Man Diana Lau, Kuok In Gabriel Yuen

Bibliographic record

VenueInternational Journal of Chemistry · 2024
Typearticle
Languageen
FieldEnvironmental Science
TopicAtmospheric and Environmental Gas Dynamics
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryComputational chemistry

Abstract

fetched live from OpenAlex

Anaerobic digestion is an organic carbon-based process and sustainable technology. In this process, empirical formulas and theoretical biomethane potentials of organic matters are two important parameters. Mass percentages of elements can be found by ultimate analysis, and then empirical formula can be calculated by the known mass percentages of elements. Other data, such as quantity amount of biomethane and theoretical biomethane potential can also be attained by calculations. Although empirical formulas are important for quantifying theoretical biomethane potentials, they are not always available in published papers. In some cases, the theoretical biomethane potential cannot be verified. This article has two purposes. First, it identifies the valid empirical formulas of organic matters. Second, it examines the correctness of a series of calculations: from mass percentages of elements to empirical formulas and from empirical formulas to theoretical biomethane potential. The mean oxidation number of organic carbons is used as an assessor that validates the empirical formulas and their corresponding mass percentages of elements. The relative percentage of theoretical biomethane potential is designed as an indicator that measures the discrepancy between the published theoretical biomethane potential and the recalculated theoretical biomethane potential.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.008
metaresearch head score (Gemma)0.065
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.008
Threshold uncertainty score0.040

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0080.065
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0030.002
Science and technology studies0.0010.005
Scholarly communication0.0040.007
Open science0.0040.002
Research integrity0.0020.006
Insufficient payload (model declined to judge)0.0050.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.297
Teacher spread0.287 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes1
Has abstractyes

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