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Record W4402912670 · doi:10.1016/j.elspec.2024.147487

Comparison of soft X-ray spectro-ptychography and scanning transmission X-ray microscopy

2024· article· en· W4402912670 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueJournal of Electron Spectroscopy and Related Phenomena · 2024
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAdvanced X-ray Imaging Techniques
Canadian institutionsCanadian Light Source (Canada)McMaster University
FundersNatural Sciences and Engineering Research Council of CanadaNational Research Council CanadaTotalHelmholtz-Zentrum Berlin für Materialien und EnergieCanada Foundation for Innovation
KeywordsX-rayPtychographyMaterials scienceMicroscopyOpticsTransmission electron microscopyChemistryCrystallographyPhysicsDiffraction

Abstract

fetched live from OpenAlex

Over the past decade advances in instrumentation and software have enabled development of spectro-ptychography (SP) as a higher spatial resolution extension of scanning transmission X-ray microscopy (STXM). Direct comparisons are made of same-area chemical state imaging of Cu nanoparticles using STXM and SP in order to compare and contrast the two approaches. We show that SP gives very similar chemical state information as STXM with significantly better spatial resolution and much higher quality images and chemical maps, on account of finer pixels in the reconstructed images. When defocused spot sizes are used (i.e., 1–3 μm, as opposed to full-focus 30–50 nm) SP data acquisition is faster and the radiation dose delivered to the sample is smaller than the corresponding STXM measurement. The limitations of SP are primarily related to the time and complexity of the ptychographic reconstruction. We argue that these documented advantages mean that SP rather than STXM should be used for more complex studies such as tomography and in situ studies, especially when radiation damage is a concern. The main point of this manuscript is to illustrate, with scientifically relevant samples, the significant advantages of SP relative to conventional STXM, with the goal of encouraging greater use of SP. • Quantitative comparisons of STM and spectro-ptychography (SP) of copper nanoparticles. • SP provides similar results with better spatial resolution, statistical precision than STXM. • SP using defocused spot sizes delivers less radiation dose thus less damage than the corresponding STXM.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.199
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.315
Teacher spread0.308 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it