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Record W4403117475 · doi:10.1016/j.jcis.2024.10.017

A versatile multilayer liquid–liquid encapsulation technique

2024· article· en· W4403117475 on OpenAlexafffund
Utsab Banerjee, Sirshendu Misra, Sushanta K. Mitra

Bibliographic record

VenueJournal of Colloid and Interface Science · 2024
Typearticle
Languageen
FieldMaterials Science
TopicPickering emulsions and particle stabilization
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of Waterloo
KeywordsEncapsulation (networking)Liquid liquidMaterials scienceNanotechnologyChemical engineeringChemistryChromatographyComputer scienceEngineering

Abstract

fetched live from OpenAlex

HYPOTHESIS: Generating multi-layer cargo using conventional methods is challenging. We hypothesize that incorporating a Y-junction compound droplet generator to encase a target core inside a second liquid can circumvent the kinetic energy dependence of the impact-driven liquid-liquid encapsulation technique, enabling minimally restrictive multi-layer encapsulation. EXPERIMENTS: Stable wrapping is obtained by impinging a compound droplet (generated using Y-junction) on an interfacial layer of another shell-forming liquid floating on a host liquid bath, leading to double-layered encapsulation. The underlying dynamics of the liquid-liquid interfaces are captured using high-speed imaging. To demonstrate the versatility of the technique, we used various liquids as interfacial layers, including magnetoresponsive oil-based ferrofluids. Moreover, we extended the technique to triple-layered encapsulation by overlaying a second interfacial layer atop the first floating interfacial layer. FINDINGS: The encapsulating layer(s) effectively protects the water-soluble inner core (ethylene glycol) inside the water bath. A non-dimensional experimental regime is established for successful encapsulation in terms of the impact kinetic energy, interfacial layer thickness, and the viscosity ratio of the interfacial layer and the outer core liquid. Using selective fluorescent tagging, we confirm the presence of individual shell layers wrapped around the core, which presents a promising pathway to visualize the internal morphology of final encapsulated droplets.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.025
Threshold uncertainty score0.227

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.297
Teacher spread0.285 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations15
Published2024
Admission routes2
Has abstractyes

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