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Record W4403409496 · doi:10.1002/aoc.7766

Heart Engineering of Photovoltaic Devices: Preparation of New Ru Dyes Using Thioindigo and Phenothiazine

2024· article· en· W4403409496 on OpenAlexaff
Mozhgan Hosseinnezhad, Sohrab Nasiri, N. Venkatramaiah, Kamaladin Gharanjig, Jean‐Michel Nunzi

Bibliographic record

VenueApplied Organometallic Chemistry · 2024
Typearticle
Languageen
FieldEngineering
TopicInnovative Microfluidic and Catalytic Techniques Innovation
Canadian institutionsQueen's University
Fundersnot available
KeywordsPhenothiazineChemistrySubstituentPhotovoltaic systemPhotochemistryMoleculeCombinatorial chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

ABSTRACT Phenothiazine and thioindigo were used as substitutes to make new Ru dyes for DSSCs. The thioindigo unit is a notable molecule with strong technical qualities in these photosensitizers. As a result, research was done on the cyano substituent as an electron‐donating group. Both theoretical and experimental methods were used to assess the complexes' optical response. A better photovoltaic response is achieved by the cyano groups' efficient bonding with the semiconductor layer. Additionally, the complexes that were formed contain two different kinds of electron accepter substituents: cyanoacrylic acid and carboxylic acid, with efficiencies of 7.42% and 4.17%, respectively. Additionally, cosensitization was investigated and analyzed utilizing N719 and two generated complexes. DSSCs made with Complex 1 and 2 and N719 have corresponding efficiency percentages of 8.86% and 9.74%.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.092
Threshold uncertainty score0.717

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.234
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2024
Admission routes1
Has abstractyes

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