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Record W4403526370 · doi:10.1016/j.seta.2024.104024

2D-3D electron transfer functions and stability of sustainable graphitic biocarbon for bipolar plate application

2024· article· en· W4403526370 on OpenAlexafffund
Nazmus Saadat, Otávio Augusto Titton Dias, Kok Long Ng, Ka Ho Chan, Shaffiq A. Jaffer, Gisele Azimi, Kristiina Oksman, Mohini Sain

Bibliographic record

VenueSustainable Energy Technologies and Assessments · 2024
Typearticle
Languageen
FieldEngineering
TopicAdvancements in Battery Materials
Canadian institutionsUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsStability (learning theory)Electron transferMaterials scienceAerospace engineeringEngineeringComputer scienceChemistry

Abstract

fetched live from OpenAlex

Biocarbon being a highly demanding renewable source of carbon is important for many applications such as soil enrichment, electronic applications, etc. In this research, sustainable waste biomass-to-energy materials conversion, kinetic, thermodynamic and electronic properties of carbonized forest biomaterials were investigated to evaluate their high-potential in bipolar plate for fuel cell application. In thermogravimetric analysis, the lignin biocarbon showed the least activation energy of 95 KJ/mol compared to 127 and 145 KJ/mol for hardwood and softwood biocarbons respectively. The crystallographic nature of carbonized ligneous and cellulosic biomaterials was also investigated, showing its intrinsic properties and exotic functionality through semi-metallic properties determined from density function theory, transmission electron microscopy and UV–Vis absorption. Finally, the electrochemical properties of bio-carbon composites were examined to prove stability and corrosion resistance comparable to metallic plates. Biocarbon composites showed high polarization resistance up to 5.96 kΩ-cm 2 with non-reactive properties, favorable to use in bipolar plates as an alternative to metallic plate which is expensive and prone to corrosion. Overall, sustainable biocarbon shows its ability as a high-performance functional material alternative to expensive nanofillers as well as to enhance the attributes of the bipolar plate composite by increasing connectivity between primary filler and insulating resin.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.604
Threshold uncertainty score0.670

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.241
Teacher spread0.235 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2024
Admission routes2
Has abstractyes

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