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Record W4403708065 · doi:10.1126/science.adq6391

Detection of interstellar 1-cyanopyrene: A four-ring polycyclic aromatic hydrocarbon

2024· article· en· W4403708065 on OpenAlexafffund
Gabi Wenzel, Ilsa R. Cooke, P. Bryan Changala, Edwin A. Bergin, Shuo Zhang, Andrew M. Burkhardt, Alex N. Byrne, Steven B. Charnley, Martin Cordiner, Zachary T. P. Fried, H. M. Sen Gupta, Martin Holdren, Andrew Lipnicky, Ryan A. Loomis, Hannah Toru Shay, Christopher N. Shingledecker, Mark A. Siebert, D. Archie Stewart, Reace H. J. Willis, Ci Xue, Anthony J. Remijan, Alison E. Wendlandt, Michael McCarthy, Brett A. McGuire

Bibliographic record

VenueScience · 2024
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAstrophysics and Star Formation Studies
Canadian institutionsUniversity of British Columbia
FundersBritish Columbia Knowledge Development FundNatural Sciences and Engineering Research Council of CanadaGoddard Space Flight CenterPlanetary Science DivisionNational Aeronautics and Space AdministrationNational Radio Astronomy ObservatoryNational Science Foundation
KeywordsPolycyclic aromatic hydrocarbonPyreneChemistryEnvironmental chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Polycyclic aromatic hydrocarbons (PAHs) are organic molecules containing adjacent aromatic rings. Infrared emission bands show that PAHs are abundant in space, but only a few specific PAHs have been detected in the interstellar medium. We detected 1-cyanopyrene, a cyano-substituted derivative of the related four-ring PAH pyrene, in radio observations of the dense cloud TMC-1, using the Green Bank Telescope. The measured column density of 1-cyanopyrene is <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"> <mml:mrow> <mml:mo>∼</mml:mo> <mml:mtext>1</mml:mtext> <mml:msup> <mml:mrow> <mml:mtext>.52×10</mml:mtext> </mml:mrow> <mml:mrow> <mml:mtext>12</mml:mtext> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> cm −2 , from which we estimate that pyrene contains up to 0.1% of the carbon in TMC-1. This abundance indicates that interstellar PAH chemistry favors the production of pyrene. We suggest that some of the carbon supplied to young planetary systems is carried by PAHs that originate in cold molecular clouds.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.250
Threshold uncertainty score0.220

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.239
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations110
Published2024
Admission routes2
Has abstractyes

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