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Record W4404008223 · doi:10.1002/ange.202416950

Combining Simple Deformations to Elicit Complex Motions and Directed Swimming of Smart Organic Crystals with Controllable Thickness

2024· article· en· W4404008223 on OpenAlexfundno aff
Xiaotong Zhu, Mengyuan Xie, Lin Gao, Liang Li, Pancě Naumov, Qi Yu, Guo‐Ming Wang

Bibliographic record

VenueAngewandte Chemie · 2024
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Surface Interaction Studies
Canadian institutionsnot available
FundersTamkeenNational Natural Science Foundation of ChinaResearch Institute Centers, New York University Abu DhabiYork UniversityNew York University Abu Dhabi
KeywordsSimple (philosophy)Materials scienceNanotechnologyChemical physicsChemistry

Abstract

fetched live from OpenAlex

Abstract The lack of control over the crystal growth in a systematic way currently stands as an unsurmountable impediment to the preparation of dynamic crystals as soft robots; in effect, the mechanical effects of molecular crystals have become a subject of scattered reports that pertain only to specific crystal sizes and actuation conditions, often without the ability to establish or confirm systematic trends. One of the factors that prevents the verification of such performance is the unavailability of strategies for effectively controlling crystal size and aspect ratio, where crystals of serendipitous size are harvested from crystallization solution. Here we devised a water‐assisted precipitation method to prepare crystals of chemical variants of 9‐anthracene derivatives with various thicknesses that respond to ultraviolet light with simple mechanical effects, including bending, splintering, and rotation. By capitalizing on the robust mechanical flexibility and deformability of crystals, we demonstrate systematic variations in crystal deformation that are further elevated in complexity to construct crystal‐based robots capable of controllable motions reminiscent of sailing and humanoid movements. The results illustrate an approach to eliminate one of the critical obstacles towards complete control over the motility of dynamic molecular crystals as microrobots in non‐aerial environments.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.462

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.270
Teacher spread0.247 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2024
Admission routes1
Has abstractyes

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