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Record W4404068380 · doi:10.1002/adfm.202410262

Integrated‐Channel Porous Transport Layers Reduce Ohmic and Mass Transport Losses in Polymer Electrolyte Membrane Electrolyzers

2024· article· en· W4404068380 on OpenAlexafffund
Alexandre Tugirumubano, Tess Seip, Lijun Zhu, Chaeyoung Tina Ham, Aida Farsi, Aimy Bazylak

Bibliographic record

VenueAdvanced Functional Materials · 2024
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsUniversity of Toronto
FundersWestern Economic Diversification CanadaCanadian Institutes of Health ResearchNatural Sciences and Engineering Research Council of CanadaCanada Research ChairsNational Research Council CanadaCanada Foundation for InnovationCanadian Light Source
KeywordsMaterials scienceElectrolyteMass transportOhmic contactPorosityPolymerMembraneWater transportChannel (broadcasting)Chemical engineeringMass transferPolymer electrolytesNanotechnologyComposite materialChromatographyLayer (electronics)ElectrodeEngineering physicsEnvironmental engineeringElectrical engineeringWater flowChemistry

Abstract

fetched live from OpenAlex

Abstract To mitigate the impacts of anthropogenic climate change, clean energy storage solutions such as hydrogen produced via polymer electrolyte membrane water electrolysis (PEMWE) are critically required. However, the porous transport layer (PTL) in current PEMWE systems lacks optimization of through‐plane and in‐plane transport properties. In this work, a PTL design with integrated channels (IC‐PTL) to improve the PTL/flow channel interface and provide additional pathways for in‐plane flow is proposed. As current density increases, the IC‐PTL reduces mass transport overpotentials by up to 71.4% compared to the baseline PTL (B‐PTL) assembly due to shorter mass transport pathways. Moreover, the IC‐PTL lowers ohmic overpotentials at high current densities by up to 42.8% due to improved interfacial contact and enhanced membrane hydration. Membrane hydration is further quantified via X‐ray synchrotron radiography analysis of changes in membrane thickness and X‐ray transmission through the membrane, revealing that the IC‐PTL assembly displays a consistently thicker membrane and recovers from thinning faster than the B‐PTL assembly. Furthermore, membrane hydration is impacted more at the catalyst layer interfaces than in the center of the membrane. As such, the addition of in‐plane transport pathways to next‐generation PTL designs to improve membrane hydration and mass transport is recommended.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.018
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.191
Teacher spread0.186 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations22
Published2024
Admission routes2
Has abstractyes

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