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Record W4404430883 · doi:10.3389/fmars.2024.1441976

Oxygen optodes on oceanographic moorings: recommendations for deployment and in situ calibration

2024· article· en· W4404430883 on OpenAlexaff
Una Kim Miller, Kristen E. Fogaren, Dariia Atamanchuk, Clare Johnson, Jannes Koelling, Isabela Le Bras, Margaret Lindeman, David Nicholson, Hilary I. Palevsky, Ellen Park, Meg Yoder, Jaime B. Palter

Bibliographic record

VenueFrontiers in Marine Science · 2024
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMarine and coastal ecosystems
Canadian institutionsDalhousie University
Fundersnot available
KeywordsOceanographyIn situCalibrationEnvironmental scienceSoftware deploymentOxygenRemote sensingGeologyMeteorologyGeographyComputer scienceChemistryPhysics

Abstract

fetched live from OpenAlex

Increasing interest in the deployment of optical oxygen sensors, or optodes, on oceanographic moorings reflects the value of dissolved oxygen (DO) measurements in studies of physical and biogeochemical processes. Optodes are well-suited for moored applications but require careful, multi-step calibrations in the field to ensure data accuracy. Without a standardized set of protocols, this can be an obstacle for science teams lacking expertise in optode data processing and calibration. Here, we provide a set of recommendations for the deployment and in situ calibration of data from moored optodes, developed from our experience working with a set of 60 optodes deployed as part of the Gases in the Overturning and Horizontal circulation of the Subpolar North Atlantic Program (GOHSNAP). In particular, we detail the correction of drift in moored optodes, which occurs in two forms: (i) an irreversible, time-dependent drift that occurs during both optode storage and deployment and (ii) a reversible and pressure-and-time-dependent drift that is detectable in some optodes deployed at depths greater than 1,000 m. The latter is virtually unidentified in the literature yet appears to cause a low-bias in measured DO on the order of 1 to 3 µmol kg−1 per 1,000 m of depth, appearing as an exponential decay over the first days to months of deployment. Comparisons of our calibrated DO time series against serendipitous mid-deployment conductivity-temperature-depth (CTD)-DO profiles, as well as biogeochemical (BGC)-ARGO float profiles, suggest the protocols described here yield an accuracy in optode-DO of ∼1%, or approximately 2.5 to 3 µmol kg−1. We intend this paper to serve as both documentation of the current best practices in the deployment of moored optodes as well as a guide for science teams seeking to collect high-quality moored oxygen data, regardless of expertise.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.017
metaresearch head score (Gemma)0.034
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.017
Threshold uncertainty score0.090

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0170.034
Meta-epidemiology (narrow)0.0030.002
Meta-epidemiology (broad)0.0010.002
Bibliometrics0.0060.004
Science and technology studies0.0010.001
Scholarly communication0.0020.004
Open science0.0060.003
Research integrity0.0040.003
Insufficient payload (model declined to judge)0.0100.019

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.230
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2024
Admission routes1
Has abstractyes

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