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Record W4404507187 · doi:10.1002/anie.202421733

Cover Picture: Mechanochemical Synthesis of Boroxine‐linked Covalent Organic Frameworks (Angew. Chem. Int. Ed. 51/2024)

2024· paratext· en· W4404507187 on OpenAlex
Ehsan Hamzehpoor, Farshid Effaty, Tristan H. Borchers, Robin S. Stein, Alexander Wahrhaftig‐Lewis, Xavier Ottenwaelder, Tomislav Friščić, Dmitrii F. Perepichka

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAngewandte Chemie International Edition · 2024
Typeparatext
Languageen
FieldMaterials Science
TopicCovalent Organic Framework Applications
Canadian institutionsConcordia UniversityMcGill University
Fundersnot available
KeywordsFront coverCover (algebra)Covalent bondMechanochemistryMaterials scienceNanotechnologyChemistryEngineeringOrganic chemistryMechanical engineering

Abstract

fetched live from OpenAlex

Mechanochemistry can be used in the synthesis of covalent organic frameworks (COFs), as reported by Xavier Ottenwaelder, Tomislav Friščić, Dmytro F. Perepichka et al. in their Research Article (e202404539). Based on this concept the first mechanochemical synthesis of boroxine-based 2D and 3D COFs with high surface area of up to 2,500 m2 g−1 was developed. The cover picture shows the structure of the monomers and the COF with the electron micrograph of the mechanochemically prepared COF in the background.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.746
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0020.002
Insufficient payload (model declined to judge)0.1430.019

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.266
Teacher spread0.256 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it