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Record W4404551351 · doi:10.26434/chemrxiv-2024-16x50

Tea Polyphenol EGCG Increases Nanoplastics Release from Plastic Cups but Mitigates Potential Detrimental Effects

2024· preprint· en· W4404551351 on OpenAlexaff
Haoxin Ye, David D. Kitts, Xiwen Wang, Yifan Wang, Tianxi Yang

Bibliographic record

VenueChemRxiv · 2024
Typepreprint
Languageen
FieldEnvironmental Science
TopicMicroplastics and Plastic Pollution
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsPolyphenolChemistryEpigallocatechin gallateFood scienceCatechinGallateBoilingBiochemistryAntioxidantNuclear chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

The presence of micro/nanoplastics in ecosystems and the potential for carry-over into daily human routines poses huge human health risks. While MNPs released from plastic packaging materials at different environmental conditions (e.g., pH, temperature) have been explored, the influence of real food ingredients (e.g., polyphenols) on plastic release has not been studied. Herein, for the first time, we investigated the effect of epigallocatechin gallate (EGCG), a relevant catechin polyphenol common to tea, on the release of nanoplastics from polystyrene (PS) cups during a heating process. We developed a novel surface-enhance Raman scattering sensor to quantify released nanoplastics in situ using EGCG-based luminescent metal phenolic network labeling strategies. The presence of added EGCG enhanced MNP release (P<0.05) when microwaved, more so than in boiling water relative to cold water control. We also observed that the higher amounts of added EGCG at the same pH and temperature caused higher amounts of nanoplastics due to the interaction of EGCG with nanoplastics. Reusing PS cups treated with EGCG in boiling water resulted in a gradual increase in nanoplastic release over 4 cycles. Of interest was the finding that EGCG also mitigated the detrimental effects of increased nanoplastics exposure in differentiated Caco-2 cell redox status in a concentration-dependent manner (P<0.05). These results imply that polyphenols as food and beverage ingredients may influence exposure to nanoplastics, but also may act to reduce nanoplastic cytotoxicity. This finding underlines the importance of broader consideration of food safety in public health discussions, focusing particularly on the composition of the food matrix and food processing and packaging applications that relate to different foods.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.190
Teacher spread0.186 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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