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A review on direct regeneration of spent lithium iron phosphate: From waste to wealth

2024· review· en· W4404871708 on OpenAlexaff
Tianyu Zhao, Yeonuk Choi, Chengqian Wu, Zhifei Zhang, Chenyang Wang, Dongfu Liu, Wenhua Xu, Xulei Huo, Weiduo Zhao, Zhongwei Zhao, Weilun Li

Bibliographic record

VenueThe Science of The Total Environment · 2024
Typereview
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsUniversity of TorontoUniversity of New BrunswickQueen's University
Fundersnot available
KeywordsRegeneration (biology)Lithium (medication)PhosphateLithium iron phosphateWaste managementIron phosphateEnvironmental scienceChemistryMedicineBiologyEngineeringEndocrinologyBiochemistry

Abstract

fetched live from OpenAlex

Lithium iron phosphate (LFP) batteries are widely used due to their affordability, minimal environmental impact, structural stability, and exceptional safety features. However, as these batteries reach the end of their lifespan, the accumulation of waste LFP batteries poses environmental hazards. Recycling these batteries is crucial for mitigating pollution risks and enabling secondary resource utilization. Traditional metallurgical recycling methods offer limited economic returns for waste LFP batteries due to their relatively low value compared to other types of cathode materials. Therefore, direct regeneration has emerged as a simpler, more cost-effective, and promising alternative. Given the stable crystal structure of LFP after decommissioning, direct regeneration by repairing lithium vacancy defects presents significant potential. This paper critically reviews the research progress on LFP regeneration, particularly focusing on developments over the past five years, and evaluates the industrial feasibility and pros and cons of these methods. Grounded in the concepts of wealth and waste, this paper adopts a novel perspective to discuss the processes of LFP degeneration and regeneration. It examines the dual attributes of waste and wealth in waste LFP batteries, elucidating the relationship and transformation between these two aspects. In particular, the paper discusses the value of LFP in its three forms-new, second-life, and waste-and the environmental and safety impacts of waste LFP batteries. It emphasizes the importance of converting waste into wealth and the role of regeneration as a potential means in the LFP recycling process. The paper objectively assesses the current challenges and opportunities, aiming to provide insights into the importance of LFP battery recycling and to explore potential avenues for advancing regeneration technologies through this comprehensive review.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.005
Threshold uncertainty score0.016

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0020.003
Science and technology studies0.0000.000
Scholarly communication0.0010.002
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0050.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.026
GPT teacher head0.285
Teacher spread0.259 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations34
Published2024
Admission routes1
Has abstractyes

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