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Record W4404905455 · doi:10.1021/acs.jafc.4c07653

NPtagM: A Tailoring Enzyme Genome Mining Toolkit and Its Application in Terpenoid P450s from Phytopathogenic Fungi

2024· article· en· W4404905455 on OpenAlexafffund
Zhanren Cong, Njeru Joe Mukoma, Qiang Yin, Bin Zhu, Lingwei She, Tom Hsiang, Lixin Zhang, Lan Jiang, Xueting Liu

Bibliographic record

VenueJournal of Agricultural and Food Chemistry · 2024
Typearticle
Languageen
FieldMedicine
TopicMicrobial Natural Products and Biosynthesis
Canadian institutionsUniversity of Guelph
FundersNational Key Research and Development Program of ChinaHigher Education Discipline Innovation ProjectState Key Laboratory of Bioreactor EngineeringScience and Technology Commission of Shanghai MunicipalityNatural Sciences and Engineering Research Council of CanadaNational Natural Science Foundation of China
KeywordsTerpenoidGenomeBiologyAspergillusAspergillus oryzaeComputational biologyGeneHeterologous expressionWorkflowEnzymeGeneticsBiochemistryRecombinant DNAComputer scienceDatabase

Abstract

fetched live from OpenAlex

Terpenoids derived from phytopathogenic fungi are major participants in interactions among microorganisms, plants, and animals. The modifications catalyzed by cytochrome P450s significantly influence the structural and bioactivity diversity of the terpenoids. To conduct genome mining of P450s in pathogenic fungi, in this study, we developed a new software called N atural P roducts Ta iloring Enzymes G enome M ining (NPtagM). By optimizing the workflow and gene prediction software, NPtagM demonstrated a 3-fold increase in the number of predicted P450s and an 8-fold reduction in runtime compared to antiSMASH. We then used it to extract 1189 dereplicated terpenoid P450s from our in-house fungal genomes. Using a sequence similarity network analysis, we identified a family that potentially produced eremophilane-type sesquiterpenoids. The heterologous expression in Aspergillus oryzae resulted in the production of two new and four known eremophilanes. Our results highlight the potential of NPtagM in genome mining for tailoring enzymes from phytopathogenic fungi.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.002
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.002
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.203
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2024
Admission routes2
Has abstractyes

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