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Record W4404952546 · doi:10.1021/acsomega.4c05072

New Re–Os Geochronological Data from the Upper Doushantuo Formation: Age Constraint on the Shuram Excursion and Implication for the Ediacaran Fluctuated Continental Weathering

2024· article· en· W4404952546 on OpenAlexaboutno aff
Zhaozhao Tan, Xuesheng Xu, Wanglu Jia, Jie Li

Bibliographic record

VenueACS Omega · 2024
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicPaleontology and Stratigraphy of Fossils
Canadian institutionsnot available
FundersNational Key Research and Development Program of ChinaState Key Laboratory of Organic GeochemistryKey Project of Research and Development Plan of Hunan Province
KeywordsGeologyRadiogenic nuclideExcursionGeochronologyWeatheringGeochemistryRadiometric datingSedimentary depositional environmentTotal organic carbonSedimentary rockPaleontologyIsotopes of carbonChemistryMantle (geology)Environmental chemistry

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide The largest negative carbon-isotope excursion in geological history has been reported by several studies of the upper Doushantuo Formation of South China, which has been correlated to the middle Ediacaran-Shuram excursion (SE). Due to a scarcity of radiometric age constraints on the excursion in South China, however, global correlations and comparisons of this event remain a debate. Here, we present Re–Os and carbon isotope data on organic-rich sediments obtained from a drill-core sample in the Chengkou area, the northeastern margin of the Yangtze Platform, and South China. The Re–Os geochronology yields a depositional age of 568 ± 15 Ma (Model 3, MSWD = 1.9, n = 13; 2σ), indicating a middle-late Ediacaran age for the upper Doushantuo Formation. This is supported by a negative δ 13 C carb excursion, which can be reliably correlated to the SE sequences. This age is consistent with the Re–Os radioisotopic dates bracketing the Shuram peaks in Northwest Canada and Oman. A compilation of 187 Os/ 188 Os and 87 Sr/ 86 Sr isotope ratios as well as the contents of redox-sensitive elements (RSE) from organic-rich sediments deposited between 635 and 540 Ma shows that the radiogenic 187 Os/ 188 Os ratios (>1.0) associated with enhanced oxidative weathering occurred at ca. 635, 580, and 560 Ma. As a result, accelerated influxes of nutrients stimulated primary productivity, promoting organic carbon burial and leading to ocean oxygenation. Additionally, elevated continental weathering could have delivered high fluxes of oxidants (e.g., sulfates) to oceans, resulting in transient ocean oxygenation. Corresponding to elevated radiogenic Os and Sr isotope ratios, the significant RSE enrichments at these three times indicate the presence of large marine RSE reservoirs and an oxygenated ocean. Therefore, the Re–Os age and initial Os isotope composition of organic-rich shale can be a sensitive tool for constraining the time interval of enhanced continental weathering and resulting pulses of ocean oxygenation during the Neoproterozoic era.

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How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.945
Threshold uncertainty score0.354

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.053
GPT teacher head0.267
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2024
Admission routes1
Has abstractyes

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