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Record W4405086194 · doi:10.1002/jsde.12819

Study of worm‐like micelles of alcohol propoxylated sulfate/alcohol ethoxylated surfactants mixtures for crude oil recovery

2024· article· en· W4405086194 on OpenAlexfundno aff
Mairis Guevara, Antonio L. Cárdenas, Ana Forgiarini

Bibliographic record

VenueJournal of Surfactants and Detergents · 2024
Typearticle
Languageen
FieldChemistry
TopicSurfactants and Colloidal Systems
Canadian institutionsnot available
FundersCenovus Energy
KeywordsPulmonary surfactantChemistrySurface tensionMicelleViscosityViscoelasticityAlkylAlcoholEnhanced oil recoveryChemical engineeringFatty alcoholPolyvinyl alcoholOrganic chemistryAqueous solutionThermodynamics

Abstract

fetched live from OpenAlex

Abstract Systems with elongated cylindrical micelles, also known as worm‐like micelles (WM) or viscoelastic surfactants (VES), have high surface activity and high viscosity, which makes them attractive in different applications such as improved oil recovery, friction reducing agents in heating and cooling fluids, household and personal care products. This study examines the carbon's chain length of alkyl propoxylated sodium sulfate anionic surfactants (C16O(PO)15S, C14O(PO)15S, and C12O(PO)15S) mixed with a nonionic ethoxylated surfactant on viscoelastic properties and interfacial tension. Results show that the larger the surfactant's carbon chain, the greater the possibility of forming WM. Furthermore, the propylene oxides' (PO) number and the nonionic surfactant's type of tail (linear or branched) is studied, not only on WM formation but also on WM/crude interfacial tension values. It is observed that the surfactant's molecular structure plays an important role in WM formation. By increasing the anionic surfactant's PO from 15 to 20 units, the maximum value of zero viscosity goes from 4.507 to 0.092 Pa.s and by changing the structure of the nonionic surfactant from linear (C12‐13EO8) to branched (C12‐14EO9) keeping the PO number of the extended surfactant constant, the zero viscosity value goes from 4.507 to 0.28 Pa.s. Likewise, the WM/crude interfacial tension reached values of the order of 10−3 mN/m in the salinity range studied, which makes these systems very interesting for polymer substitution in enhanced crude oil recovery (EOR).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.000
Threshold uncertainty score0.001

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.038
GPT teacher head0.296
Teacher spread0.259 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2024
Admission routes1
Has abstractyes

Explore more

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