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Valorization of lignocellulosic biomass forest residues in quebec via the integrated hydropyrolysis and hydroconversion (IH2) technology: A review

2024· review· en· W4405088477 on OpenAlexaffabout
Aravind Ganesan, Olivier Rezazgui, Jimmy Barco Burgos, Patrice Mangin, Simon Barnabé

Bibliographic record

VenueBiomass and Bioenergy · 2024
Typereview
Languageen
FieldEngineering
TopicThermochemical Biomass Conversion Processes
Canadian institutionsUniversité du Québec à Trois-Rivières
Fundersnot available
KeywordsBiomass (ecology)Lignocellulosic biomassEnvironmental scienceWaste managementPulp and paper industryEnvironmental protectionAgroforestryBiofuelEngineeringAgronomyBiology

Abstract

fetched live from OpenAlex

Lignocellulosic biomass residues from Quebec's forests, such as branches and logging residues, can be thermochemically converted into hydrocarbons-rich renewable fuels, offering a sustainable alternative to fossil oil in transportation. Integrated Hydropyrolysis and Hydroconversion (IH 2 ) has emerged as a promising biorefinery technology for transforming diverse biomass feedstocks into bio-oil with properties akin to petroleum, achieving approximately 45 % carbon conversion and 27 wt% bio-oil yield. Optimal conditions for catalytic fast hydropyrolysis (CFHP) include temperatures of 400–450 °C, hydrogen pressures of 20–30 bar, and biomass heating rates of 100–500 °C/min. For the catalytic hydroconversion (CHC) stage, lower temperatures of 250–400 °C with similar hydrogen pressures are beneficial. To enhance bio-oil quality and yield, feed particle sizes below 1 mm are recommended for enhanced heat transfer. While clean hydrogen for IH 2 could be produced from electrolysis and biomass, an alternative co-CFHP process using hydrogen-rich bio-based solvents, UEO, and waste plastics can mitigate the need for external hydrogen, high pressures, and complex setups. This can be operated with or without an optional hydrotreatment stage based on required product specifications. The results highlight some potential catalyst alternatives to TMS like TMO, TMP, TMN , and TMC that could improve deoxygenation efficiency and reduce associated challenges. Carbonaceous supports like biochars can replace conventional Al 2 O 3 and achieve better performance w.r.t coking, surface functionalities, metal dispersibility, and sensitivity to deoxygenation by-products. Additionally, fluidized bed reactors are suggested for their scalability and effectiveness in facilitating consistent reactions. Overall, this study underscores the viability of IH 2 and identifies critical areas for further research to achieve demonstration-scale feasibility.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.886
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.002
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.231
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2024
Admission routes2
Has abstractyes

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