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Record W4405095404 · doi:10.1016/j.decarb.2024.100091

Atomically dispersed metal site materials for hydrogen energy utilization: Theoretical and experimental study in fuel cells and water electrolysis

2024· article· en· W4405095404 on OpenAlexaff
Xinxing Zhan, Xin Tong, Hao Ye, Zijian Gao, Tian Juan, Jinliang Zhuang, Gaixia Zhang, Shuhui Sun

Bibliographic record

VenueDeCarbon · 2024
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsInstitut National de la Recherche ScientifiqueÉcole de Technologie Supérieure
FundersDepartment of Education of Guizhou ProvinceGuizhou Science and Technology DepartmentNational Natural Science Foundation of ChinaEducational Testing Service
KeywordsElectrolysisHydrogen fuelFuel cellsElectrolysis of waterMaterials scienceHydrogenMetalHydrogen productionWaste managementChemical engineeringEnvironmental scienceMetallurgyChemistryEngineeringElectrodeElectrolyte

Abstract

fetched live from OpenAlex

Atomically dispersed metal site (ADMS) materials have emerged as a promising class of materials for electrocatalysis reactions in the field of energy conversion. Characterized by individual metal atoms dispersed on suitable supports, ADMS materials provide unique catalytic sites with highly tunable electronic structures. This review summarizes recent advancements in the field, with a focus on the critical roles of support materials, coordination environments, and the mechanisms underlying catalytic activity at the atomic level. First, commonly used density functional theory (DFT) simulations are reviewed, emphasizing their pivotal role in elucidating reaction mechanisms and predicting the behavior of ADMS in electrochemical reactions for hydrogen energy utilization. Then, advancements in ADMS for half-cell electrochemical reactions, including oxygen evolution reaction, hydrogen evolution reaction, and oxygen reduction reaction, as well as their applications in fuel cells and water splitting, are summarized. Finally, the challenges and future prospects of ADMS are discussed. This review underscores the transformative potential of ADMS in electrocatalysis, paving the way for innovative and sustainable energy conversion technologies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.043
Threshold uncertainty score0.729

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.237
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2024
Admission routes1
Has abstractyes

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