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Record W4405483579 · doi:10.1016/j.rset.2024.100099

Toward sustainable propylene: A comparison of current and future production pathways

2024· article· en· W4405483579 on OpenAlexafffund
Parsa Shirzad, Ivan Kantor

Bibliographic record

VenueRenewable and Sustainable Energy Transition · 2024
Typearticle
Languageen
FieldChemistry
TopicZeolite Catalysis and Synthesis
Canadian institutionsConcordia University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsProduction (economics)Current (fluid)Biochemical engineeringSustainable productionEnvironmental scienceEngineeringEconomics

Abstract

fetched live from OpenAlex

Propylene, a fundamental chemical, has witnessed a significant surge in demand in recent decades, establishing itself as the second most primary intermediate compound after ethylene. Propylene manufacturing currently depends on non-renewable resources, specifically naphtha or propane from fossil sources. The conventional methods are economically feasible and mature; however, they emit greenhouse gases and consume non-renewable resources. Therefore, it is necessary to transition to more sustainable production methods. This review aims to provide and analyze many possible routes for the production of propylene using sustainable resources. The categorization of these pathways is determined by the raw material employed for the manufacture of propylene. Out of the several paths considered, bio-propane dehydrogenation stands out as a viable option for producing propylene in the future. Furthermore, this study examines and reports on the analysis of catalyst selection, the design of operating conditions, and the yield and selectivity of propylene in each pathway. Zeolite-based catalysts, particularly ZSM-5, exhibit remarkable selectivity in propylene synthesis across several processes. To fully comprehend the sustainability and feasibility of these paths, this research also reviews environmental impact and techno-economic metrics of several established propylene production methods.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.531
Threshold uncertainty score0.894

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.237
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2024
Admission routes2
Has abstractyes

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