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Record W4405484320 · doi:10.1016/j.apmt.2024.102558

Lead-free single and dual-filler loaded polychloroprene X-ray shielding nanocomposites

2024· article· en· W4405484320 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueApplied Materials Today · 2024
Typearticle
Languageen
FieldMaterials Science
TopicRadiation Shielding Materials Analysis
Canadian institutionsWestern UniversityUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsElectromagnetic shieldingNanocompositeComposite materialFiller (materials)Materials scienceNeopreneDual (grammatical number)Lead (geology)X-rayOpticsNatural rubberPhysics

Abstract

fetched live from OpenAlex

Flexible polymers loaded with metal particles other than Pb are emerging composites for X-ray shielding applications. In this study, the X-ray radiation shielding performance of bismuth oxide (Bi 2 O 3 ) and barium sulfate (BaSO 4 ) metal particles embedded in polychloroprene (CR) matrix was evaluated with X-ray tube voltages of 80, 120 and 135 kVp. BaSO 4 and Bi 2 O 3 micro- and nanoparticle were synthesized and successfully loaded (0 – 60 parts per hundred, phr) as singular and dual functional additive of CR matrix . At 80 kVp, CR loaded with BaSO 4 particles (Ba-CR) showed enhanced attenuation capabilities (linear attenuation coefficient, μ = 2.56 cm -1 ). However, at 120 and 135 kVp, Bi-CR composites showed better shielding performance (μ = 1.813 cm -1 and μ = 1.621 cm -1 at 120 and 135 kVp, respectively). The dual-filler composites (Ba/Bi-CR composites) have shown a synergistic effect at 20 phr particle loading (10Ba/10Bi-CR), showing enhanced attenuation in nearly all tube voltages. The results of the study pointed out a promising potential for CR composites with BaSO 4 and/or Bi 2 O 3 additives for lead-free X-ray protective material with more flexibility, light weightiness, and environmentally friendly attributes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Scholarly communication, Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0020.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0050.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.228
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it