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Record W4405702159 · doi:10.1021/acsenergylett.4c02852

Economic Viability of Integrated CO<sub>2</sub> Capture and Conversion

2024· article· en· W4405702159 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS Energy Letters · 2024
Typearticle
Languageen
FieldEngineering
TopicCarbon Dioxide Capture Technologies
Canadian institutionsCanadian Institute for Advanced ResearchUniversity of British Columbia
FundersCanada First Research Excellence FundCanada Foundation for InnovationNatural Sciences and Engineering Research Council of CanadaCanada Research ChairsCanadian Institute for Advanced Research
KeywordsEnvironmental scienceProcess engineeringMaterials scienceWaste managementChemistryEngineering

Abstract

fetched live from OpenAlex

The capture of CO 2 using alkaline solutions requires significant thermal energy to release CO 2 from a (bi)carbonate-enriched solution. This release of CO 2 can instead be performed electrochemically with a “bicarbonate electrolyzer”. The bicarbonate electrolyzer forms acid equivalents to convert a (bi)carbonate-enriched eluent from a CO 2 capture unit into CO 2 and, in turn, an upgraded carbon product such as CO and ethylene. There exists a tension for this closed-loop cycle to be put into practice: a smaller CO 2 capture unit is required when using a more caustic CO 2 capture solution, yet the electrolyzer works more effectively at a lower pH. Here, we elaborate on three different methods to align different pH regimes to couple air capture to CO 2 electrolysis. We also use a mass-balance model to assess the commercial viability of a reactive carbon capture system that integrates the CO 2 capture unit with a bicarbonate electrolyzer to show a levelized CO breakeven price below $1 kg CO –1 . These economics, coupled with the other practical advantages of providing an electrolyzer with a liquid feedstock, present a compelling case for reactive carbon capture.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.594

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.172
Teacher spread0.169 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it