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Record W4405800233 · doi:10.3390/toxics13010006

Global Assessment of Emerging Contaminant Removal in Wastewater Treatment Plants: In Silico Hazard Screening and Risk Evaluation

2024· article· en· W4405800233 on OpenAlexaff
Arianna Sgariboldi, Elena Posté, Nicola Chirico, Alessandro Sangion, Marco Evangelista, Cristiana Morosini, Andrea Re, Vincenzo Torretta, Ester Papa

Bibliographic record

VenueToxics · 2024
Typearticle
Languageen
FieldEnvironmental Science
TopicPharmaceutical and Antibiotic Environmental Impacts
Canadian institutionsARC Resources (Canada)
FundersMinistero dell’Istruzione, dell’Università e della Ricerca
KeywordsBioaccumulationHazardous wasteQuantitative structure–activity relationshipEnvironmental scienceEnvironmental impact of pharmaceuticals and personal care productsEnvironmental chemistryBioconcentrationHazard analysisRisk assessmentWastewaterAquatic environmentHazardBiochemical engineeringChemistryComputer scienceEnvironmental engineeringBiologyEcologyEngineering

Abstract

fetched live from OpenAlex

Pharmaceuticals and personal care products (PPCPs) are emerging contaminants (ECs), whose presence in the environment is of increasing concern due to their widespread use and possible detrimental effects on wildlife and humans. These chemicals may present multiple hazardous properties such as environmental persistence, toxicity, high mobility, and the potential for bioaccumulation. In this study, extended bibliographic research was conducted to characterize the removal efficiency (RE) of PPCPs in wastewater treatment plants (WWTPs) considering different technologies. Measured values of RE were collected from the literature or calculated for 251 compounds. The molecular structure of the 245 PPCPs were used as the input to generate predictions of multiple properties using several QSAR tools, such as the OECD Toolbox, OPERA, EPI Suite™, and QSAR-ME Profiler. These predictions were compared to regulatory thresholds to identify hazardous chemicals and to screen persistent, mobile and toxic (PMT) or persistent, bioaccumulative and toxic (PBT) substances. Finally, chemicals were prioritized by combining values of RE and QSAR predictions for multiple properties. A total of 16 out of the 245 molecules were prioritized as the most hazardous compounds to the aquatic environment and, among these, six were associated with potential risk due to their exposure concentrations reported in the literature.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score0.011

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.034
GPT teacher head0.349
Teacher spread0.315 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2024
Admission routes1
Has abstractyes

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