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Record W4406166322 · doi:10.1126/sciadv.ads1459

Role of the stratosphere in the global mercury cycle

2025· article· en· W4406166322 on OpenAlexaff
Alfonso Saiz‐Lopez, Carlos A. Cuevas, A. Ulises Acuña, Juan Antonio Añel, Anoop S. Mahajan, Laura de la Torre, Wuhu Feng, Juan Z. Dávalos, Daniel Roca‐Sanjuán, Douglas E. Kinnison, Javier Carmona‐García, Rafael P. Fernández, Qinyi Li, Jeroen E. Sonke, Aryeh Feinberg, Juan Carlos Gómez Martı́n, Julián Villamayor, Peng Zhang, Yanxu Zhang, Christopher S. Blaszczak-Boxe, Oleg Travnikov, Fei Wang, Johannes Bieser, Joseph S. Francisco, J. M. C. Plane

Bibliographic record

VenueScience Advances · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicMercury impact and mitigation studies
Canadian institutionsUniversity of Manitoba
FundersSchweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
KeywordsStratosphereMercury (programming language)TroposphereTropopauseEnvironmental scienceAtmospheric sciencesEnvironmental chemistryChemistryPhysics

Abstract

fetched live from OpenAlex

Mercury (Hg) is a global pollutant with substantial risks to human and ecosystem health. By upward transport in tropical regions, mercury enters into the stratosphere, but the contribution of the stratosphere to global mercury dispersion and deposition remains unknown. We find that between 5 and 50% (passing through the 400-kelvin isentropic surface and tropopause, respectively) of the mercury mass deposited on Earth's surface is chemically processed in the lower stratosphere. Our results show the stratosphere as a unique chemical environment where elemental mercury is efficiently converted to long-lived oxidized species. Subsequent downward transport contributes substantially to the oxidized mercury burden in the troposphere. The results show that the stratosphere facilitates the global dispersion of large amounts of mercury from polluted source regions to Earth's remote environments. We find that stratospheric transport is as important as tropospheric transport in interhemispheric mercury dispersion. Future projections suggest that expected changes in atmospheric circulation will increase the transport of mercury into the stratosphere.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.130
Threshold uncertainty score0.465

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.281
Teacher spread0.275 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations22
Published2025
Admission routes1
Has abstractyes

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