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Record W4406328962 · doi:10.5194/egusphere-2024-3736

Global Ground-based Tropospheric Ozone Measurements: Reference Data and Individual Site Trends (2000–2022) from the TOAR-II/HEGIFTOM Project

2025· preprint· en· W4406328962 on OpenAlexaff
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, H. G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, V. Thouret, Pawel Wolff, Peter Effertz, D. W. Tarasick, Deniz Poyraz, G. Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, B. J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, Ralf Sussmann

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsUniversity of TorontoEnvironment and Climate Change Canada
FundersOffice of Polar ProgramsFonds De La Recherche Scientifique - FNRSNational Aeronautics and Space AdministrationNational Oceanic and Atmospheric AdministrationNational Science Foundation
KeywordsTropospheric ozoneTroposphereEnvironmental scienceOzoneAtmospheric sciencesNorthern HemisphereMeteorologyLatitudeClimatologyGeographyGeology

Abstract

fetched live from OpenAlex

Abstract. Tropospheric ozone trends from models and satellites are found to diverge. Ground-based (GB) observations are used to reference models and satellites but GB data themselves might display station biases and discontinuities. Re-processing with uniform procedures, the TOAR-II Working Group Harmonization and Evaluation of Ground-based Instruments for Free-Tropospheric Ozone Measurements (HEGIFTOM) homogenized public data from 5 networks: ozonesondes, In-service Aircraft for a Global Observing System (IAGOS) profiles, solar absorption Fourier-Transform Infrared (FTIR) spectrometer measurements, Lidar observations, and Dobson Umkehr data. Amounts and uncertainties for total tropospheric ozone (“TrOC”, surface to 300 hPa), free and lower tropospheric ozone, are calculated for each network. We report trends (2000 to 2022) for these segments using Quantile Regression (QR) and Multiple Linear Regression (MLR) for 55 datasets, including 6 multi-instrument stations. The findings: (1) Median TrOC trends computed with QR and MLR trends are essentially the same; (2) Pole-to-pole, across all longitudes, TrOC trends fall within +3 ppbv/decade to -3 ppbv/decade, equivalent to (-4 % to + 8 %)/decade depending on site. (3) The greatest fractional increases occur over most tropical/subtropical sites with decreases at northern high latitudes but these patterns are not uniform. (4) Post-COVID trends are smaller than pre-COVID trends for Northern Hemisphere mid-latitude sites. In summary, this analysis conducted in the frame of TOAR-II/HEGIFTOM shows that high-quality, multi-instrument, harmonized data over a wide range of ground sites provide clear standard references for TOAR-II models and evolving tropospheric ozone satellite products for 2000–2022.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.046
Threshold uncertainty score0.091

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0020.005
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.094
GPT teacher head0.289
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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