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Record W4406364849 · doi:10.1016/j.jnucmat.2025.155625

The role of pressure in carburisation: Crack dynamics in Type 316H austenitic stainless steel under CO2 environments

2025· article· en· W4406364849 on OpenAlexaff
Mariia Zimina, Alexander Warren, Lawrence Coghlan, Peter Thomas, Marc Chevalier, P. E. J. Flewitt, T. Martin

Bibliographic record

VenueJournal of Nuclear Materials · 2025
Typearticle
Languageen
FieldEngineering
TopicMicrostructure and Mechanical Properties of Steels
Canadian institutionsSaint John Regional HospitalCanada East Spine CentreUniversity of New Brunswick
FundersEngineering and Physical Sciences Research CouncilEDF EnergyInnovate UKUniversity of BristolRoyal Academy of Engineering
KeywordsAusteniteDynamics (music)Materials scienceMolecular dynamicsHigh pressureAustenitic stainless steelMetallurgyNuclear engineeringChemistryThermodynamicsPhysicsEngineeringComputational chemistryMicrostructureCorrosion

Abstract

fetched live from OpenAlex

The oxidation and carburisation of steel in advanced gas-cooled nuclear reactors limit the life of key components during plant operation. To achieve a mechanistic understanding of the origin of carburisation phenomena, simulation or replication of service exposure conditions is needed. Laboratory tests are usually performed to accelerate processes such as crack initiation and growth in the material, and to simulate plant conditions as precisely as possible. This paper describes the results of carburisation data analysis of AISI Type 316H stainless steel under several CO 2 gas exposure conditions. The behaviour of ex-service welded pipe components from advanced gas-cooled reactors at service temperature and pressure is compared to a range of specimens loaded and cracked in air and under surrogate/simulated CO 2 conditions. Both atmospheric pressure and pressurised CO 2 gas (4.14 MPa) conditions were studied. Microstructural characterisation of the crack tip region and the bulk/matrix of the specimens was performed using advanced electron microscopy techniques. The regions ahead of the crack tips were systematically analysed as they have a potential to significantly influence crack propagation behaviour. This study shows a significant effect of carburisation at the crack tip compared to the bulk of the material, but only for pressurised CO 2 conditions, whereas atmospheric pressure CO 2 conditions more closely resembled the specimen exposed in air. Importantly, this study reveals that in simulated experiments, pressurised CO 2 environments are essential to replicate the carburisation behaviour observed in ex-service conditions. • Both ex-service 316H austenitic steel and 316H specimens exposed to pressurised CO 2 show carburisation ahead of crack tips. • Air and atmospheric pressure CO 2 tests fail to replicate this carburisation behaviour. • The proposed mechanism reflects the role of pressurised CO 2 environment on carburisation of 316H steel.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.485
Threshold uncertainty score0.236

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.196
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2025
Admission routes1
Has abstractyes

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