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Record W4406627698 · doi:10.3749/2400026

Kreiterite, CsLi2Fe+3(Si4O10)F2, a New Cesium Mica from the Darai-Pioz Alkaline Massif, Tajikistan

2025· article· en· W4406627698 on OpenAlexaff
Atali A. Agakhanov, Leonid A. Pautov, Igor V. Pekov, Vladimir Yu. Karpenko, Oleg I. Siidra, Е. Соколова, F. C. Hawthorne, А. Р. Файзиев, Anatoly V. Kasatkin, И. М. Куликова, Vyacheslav A. Muftakhov

Bibliographic record

VenueThe Canadian Journal of Mineralogy and Petrology · 2025
Typearticle
Languageen
FieldMaterials Science
TopicCrystal Structures and Properties
Canadian institutionsUniversity of Manitoba
Fundersnot available
KeywordsMassifMicaCaesiumGeologyGeochemistryChemistryPaleontologyInorganic chemistry

Abstract

fetched live from OpenAlex

Abstract Kreiterite, CsLi2Fe+3(Si4O10)F2, a new cesium trioctahedral mica was discovered in the Darai-Pioz alkaline massif (Tajikistan). It is named after the Russian geologist, Prof. Vladimir Mikhailovich Kreiter (1897–1966). Kreiterite occurs as lamellar grains or flakes up to 0.2 mm across, irregular in shape and usually slightly deformed, in quartz-pectolite aggregates within so-called “quartz lumps”, the rocks consisting mainly of granular quartz. The mineral is colorless and transparent with vitreous luster. Mohs hardness is 2½, Dmeas. is 3.33(2) g/cm3, and Dcalc. is 3.342 g/cm3. The new mineral is optically biaxial (−) with α = 1.596(2), β = 1.605(2), γ = 1.607(2), 2V(calc) = −50°. It is monoclinic, space group C2/m, C2, or Cm (polytype 1M), a = 5.240(2) Å, b = 9.054(4) Å, c = 10.767(4) Å, β = 99.58(4)°, V = 503.4(6) Å3, and Z = 2. The strongest lines in the powder diffraction pattern are (d Å, I %, hkl): 4.49, 31, (1 1 0); 3.94, 31, (1 1 1); 3.70, 47, ( 1 2), ( 2); 3.45, 36, (0 2 2); 3.00, 34, ( 1 ), ( 3); 2.652, 17, (0 0 4); 2.610, 72, ( 0 1), (1 3 0), ( 3 0); 2.583, 100, (2 0 0), ( 3 1); 2.241, 38, (2 2 0); 2.190, 67, ( 3 3). Chemical analysis by electron microprobe and SIMS (for H2O and Li2O) gave SiO2 47.37, TiO2 0.99, Al2O3 0.29, MgO 0.40, Fe2O3 13.18, ZnO 0.12, K2O 0.02, Cs2O 27.37, Li2O 5.90, H2O 1.28, F 4.77, −O=F −2.01, total 99.68 wt.% The empirical formula, based on 12 (O+F), is Cs0.99Li2.01(Fe3+0.84Ti0.06Mg0.05Al0.03Zn0.01)Σ0.99Si4.01O10(F1.28OH0.72)Σ2. Kreiterite is a ferric-iron analogue of sokolovaite and gorbunovite and the lithium ferric-iron analogue of garmite.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.523
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.217
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations0
Published2025
Admission routes1
Has abstractyes

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