Sabatier Principle Inspired Bifunctional Alloy Interface for Stable and High‐Depth Discharging Zinc Metal Anodes
Bibliographic record
Abstract
Abstract Achieving stable Zn anodes that can effectively couple with Zn‐free cathodes is essential for advancing high‐performance Zn metal batteries. Here, we propose a Sabatier principle inspired bifunctional transition‐metal (TM) interface to enable homogeneous Zn dissolution during discharging and dendrite‐free Zn deposition during charging. Among various TM‐coated Zn (TM@Zn) electrodes, Cu@Zn exhibits the highest reversibility and structural stability, attributed to the optimal interaction between Cu and Zn. The heteroatomic interaction‐dependent electrochemical performance parallels the Sabatier principle. Morphological analyses reveal that bare Zn anodes display detrimental etching pits during stripping, which is different from the uniform dissolution for Cu@Zn electrodes. During subsequent plating, the conductive interface serves as a secondary current collector for uniform Zn deposition in Cu@Zn, thus demonstrating a bifunctional nature. Atomic observations disclose the working mechanisms of this interface as a gradual phase transition from Cu to CuZn5 during cycling. The Cu@Zn anodes exhibit an ultralong cycling lifespan of over 8000 h at a low current of 1 mA cm−2 and over 250 h at a high depth of discharge of 80 %. They also demonstrate practical feasibility by maintaining 88.7 % capacity retention after 1000 cycles in Cu@Zn||VO2 full cells. This work provides new insights into the Sabatier chemistry inspired bifunctional layers for Zn metal battery system.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".