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Record W4407087279 · doi:10.1016/j.chemgeo.2025.122665

Using oxygen (δ18O, δ17O) and hydrogen (δ2H) isotopes in the Northern Limb of the Bushveld Igneous Complex to assess the extent of footwall contamination

2025· article· en· W4407087279 on OpenAlexafffund
Sharlotte C. Mkhonto, Matthew I. Leybourne, Derek R. Knaack, Pedro J. Jugo, Daniel Layton‐Matthews, Danie F. Grobler

Bibliographic record

VenueChemical Geology · 2025
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeological and Geophysical Studies
Canadian institutionsStillwater (Canada)Laurentian UniversityArthur B. McDonald-Canadian Astroparticle Physics Research InstituteQueen's University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsGeologyGeochemistryIgneous rockδ18OIsotopes of oxygenContaminationHydrogen isotopeIsotopeHydrogenStable isotope ratioChemistry

Abstract

fetched live from OpenAlex

The Platreef in the Northern Limb is in the same stratigraphic position as the Critical Zone (i.e. Merensky Reef) in the Eastern and Western limbs of the Bushveld Igneous Complex (BIC). However, in some areas, the Platreef is in direct contact with Archean granitic gneisses and Transvaal Supergroup metasedimentary rocks. Although there is significant evidence of assimilation of Transvaal Supergroup metasedimentary rocks in the southern parts of the Platreef, there is no consensus on the extent of contamination and if contamination is proximal or distal to the Pt, Pd, Au mineralized zone/Merensky Reef equivalent. For this study, we report δ’ 18 O, Δ’ 17 O, and δ 2 H values of samples from the downdip portion of the Flatreef (part of the Platreef) on Turfspruit. The results show that δ’ 18 O values range from ∼4 to 7 ‰ in intervals with little to no evidence of assimilation and can reach up to 17 ‰ in intervals with evidence of pervasive assimilation. The δ’ 18 O values in areas with no evidence of assimilation are similar to previously reported values in the Eastern and Western limbs of the BIC. The Δ’ 17 O values range from −0.200 to 0.050 ‰ throughout the stratigraphy. Most of the positive Δ’ 17 O values are associated with intervals showing evidence of assimilation. The δ 2 H values (which range from −92 to −30 ‰) show no correlation between intervals with pervasive assimilation and those with little to no contamination. Samples from the Turfspruit area of the Northern Limb have δ’ 18 O values of -5.53 to 17.14 ‰ which shows the extent of footwall assimilation of the Transvaal metasedimentary rocks. The triple oxygen isotope values show that the Northern Limb of the BIC records two separate episodes of crustal contamination: (1) a proximal contamination by local footwall lithologies; and (2) a deeper, more pervasive (with respect to the entire BIC) contamination, prior to injection of the BIC magmas into the middle/upper crust.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.023
Threshold uncertainty score0.356

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.044
GPT teacher head0.249
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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