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Optimizing the Temperature Sensitivity of the Isoprene Emission Model MEGAN in Different Ecosystems Using a Metropolis-Hastings Markov Chain Monte Carlo Method

2025· preprint· en· W4407171621 on OpenAlexafffund
Christian DiMaria, Dylan B. A. Jones, Valerio Ferracci, A. Anthony Bloom, H. M. Worden, Roger Seco, Lejish Vettikkat, Ana María Yáñez‐Serrano, Alex Guenther, Alessandro Araùjo, Allen H. Goldstein, B. Langford, James M. Cash, Neil Harris, Luke Brown, Riikka Rinnan, Siegfried Schobesberger, Thomas Holst, John E. Mak

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldPhysics and Astronomy
TopicScientific Research and Discoveries
Canadian institutionsUniversity of Toronto
FundersEuropean Social FundAgencia Estatal de InvestigaciónNatural Sciences and Engineering Research Council of CanadaNatural Environment Research CouncilCanadian Space AgencyJet Propulsion LaboratoryPolarforskningssekretariatetFinanciadora de Estudos e ProjetosVetenskapsrådetNational Aeronautics and Space AdministrationMinistério da Ciência, Tecnologia e InovaçãoBundesministerium für Bildung und ForschungMax-Planck-GesellschaftNational Research FoundationDanmarks GrundforskningsfondEuropean Regional Development FundInstituto Nacional de Pesquisas da AmazôniaFundação de Amparo à Pesquisa do Estado do AmazonasCalifornia Institute of TechnologyUniversity of Oxford
KeywordsMarkov chain Monte CarloMetropolis–Hastings algorithmIsopreneMonte Carlo methodSensitivity (control systems)Markov chainStatistical physicsEnvironmental scienceComputer sciencePhysicsMathematicsStatisticsEngineeringMachine learning

Abstract

fetched live from OpenAlex

Isoprene is a reactive hydrocarbon emitted to the atmosphere in large quantities by terrestrial vegetation. Annual total isoprene emissions exceed 300 Tg a-1, but emission rates vary widely among plant species and are sensitive to meteorological and environmental conditions including temperature, sunlight, and soil moisture. Due to its high reactivity, isoprene has a large impact on air quality and climate pollutants such as ozone and aerosols. It is also an important sink for the hydroxyl radical which impacts the lifetime of the important greenhouse gas methane along with many other trace gas species. Modelling the impacts of isoprene emissions on atmospheric chemistry and climate requires accurate isoprene emission estimates. These can be obtained using the empirical Model of Emissions of Gases and Aerosols from Nature (MEGAN), but the parameterization of this model is uncertain due in part to limited field observations. In this study, we use ground-based measurements of isoprene concentrations and fluxes from 11 field sites to assess the variability of the isoprene emission temperature response across ecosystems. We then use these observations in a Metropolis-Hastings Markov Chain Monte Carlo (MHMCMC) data assimilation framework to optimize the MEGAN temperature response function. We find that the performance of MEGAN can be significantly improved at several high-latitude field sites by increasing the modelled sensitivity of isoprene emissions to past temperatures. At some sites, the optimized model was nearly 4 times more sensitive to temperature than the unoptimized model. This has implications for air quality modelling in a warming climate.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.109
Threshold uncertainty score0.990

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.002
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.314
Teacher spread0.288 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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