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Record W4407302544 · doi:10.1016/j.gexplo.2025.107713

Unconformity-related mineralization and fluid transfers in the northern Aquitaine Basin (France) revealed by fluid inclusions and S-Sr isotopes studies

2025· article· en· W4407302544 on OpenAlexaff
Loïc Bouat, Pierre Strzerzynski, Véronique Gardien, Guillaume Barré, Yannick Branquet, Jérémie Melleton, Régis Mourgues

Bibliographic record

VenueJournal of Geochemical Exploration · 2025
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeological and Geochemical Analysis
Canadian institutionsUniversité Laval
FundersCentre National de la Recherche Scientifique
KeywordsFluid inclusionsUnconformityGeologyMineralization (soil science)GeochemistryIsotopes of strontiumIsotopeStructural basinStable isotope ratioMineralogyQuartzPaleontologySedimentary rockSoil science

Abstract

fetched live from OpenAlex

In sedimentary basins, unconformity between basement and sediments is the ideal site where fluids from different sources can flow and mix, initiating the formation of ore deposits. In western Europe there are numerous F-Pb-Zn-Ba (±Ag, Ge) basin-hosted deposits located near the unconformity between Mesozoic Basins and the Variscan basement as for example the deposits of the Vendée Coast (France) containing fluorite, baryte, pyrite and quartz. Here, microthermometric data on the primary fluid inclusions of these minerals indicate salinity ranging from 1 to 20 wt% eq. NaCl and homogenization temperatures between 100 and 390 °C. We interpret these data as resulting of a fluids circulation in the ore deposit zone, with an early incursion of basin brines expelled by the leaching of Hettangian evaporites buried several tens of kilometers away, followed by an ascent of basement-derived fluids and, finally, a recharge of seawater. In other French deposits, the δ 34 S isotopes of baryte are also consistent with a source of fluids from buried evaporites. The 87 Sr/ 86 Sr ratio of baryte demonstrates a crustal source of elements associated with brines-leached base metals and F Ba. The process of buried-derived evaporites brines altering the basement along the unconformity is ubiquitous in all unconformity deposits in France. With our results, we confirm that the basin deposits in the Southeastern Massif Central occur along structures formed during Tethys rifting at around 200 Ma, whereas in the Western part they form at ca. 145 Ma in link with the opening of the Bay of Biscay. This highlights that these basin-hosted deposits are preferentially formed during extensional activity in rifting settings, rather than in compressive settings. • Fluid inclusions analysis depict a sequenced mixing of three fluids • δ 34 S isotopes trace evaporitic source of sulfur and a Rayleigh fractionation • 87 Sr/ 86 Sr reveals a crustal contribution associated with F-Ba and base metals concentration • Two periods of rifting favorable to basin-hosted mineralization near unconformity in Western Europe

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.409
Threshold uncertainty score0.286

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.229
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2025
Admission routes1
Has abstractyes

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