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Life cycle assessment of turning hydrogen sulfide recovered from sea waters into clean hydrogen

2025· article· en· W4407640373 on OpenAlexaff
Muhammad Ishaq, İbrahim Dinçer

Bibliographic record

VenueResources Conservation and Recycling · 2025
Typearticle
Languageen
FieldEngineering
TopicIndustrial Gas Emission Control
Canadian institutionsUniversity of Ontario Institute of Technology
Fundersnot available
KeywordsHydrogen sulfideHydrogenEnvironmental scienceWaste managementLife-cycle assessmentEnvironmental chemistryOceanographyEngineeringChemistryMetallurgyMaterials scienceEconomicsGeologySulfur

Abstract

fetched live from OpenAlex

The present work aims to conduct a comprehensive life cycle assessment (LCA) of the hydrogen production system utilizing hydrogen sulfide (H 2 S) obtained from the sources available in the sea waters, such as the Black Sea. A robust LCA methodology is developed by coupling the process simulation results from the Aspen Plus with the LCA capabilities of the openLCA. The H 2 S is extracted from the bottom of the Black Sea and employed as a feedstock for a thermochemical cycle to produce hydrogen. The environmental performance is characterized by six harmonized indicators: global warming potential (GWP), acidification potential (AP), particulate matter (PM), eutrophication freshwater potential (EP), ozone layer depletion (ODP), and resource use, minerals, and metals (ADP). The analysis of alternate oxygen carriers within the LCA framework demonstrates that the Fe 2 O 3 /FeS redox pair results in 66.28 % less global warming potential than the baseline ZnO/ZnS redox pair, highlighting the significance of material selection in optimizing environmental performance. The life cycle quality index and life cycle irreversibility index are considered 28.92 % and 71.09 % respectively.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.630
Threshold uncertainty score0.657

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.246
Teacher spread0.234 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2025
Admission routes1
Has abstractyes

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