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Record W4407702268 · doi:10.1002/chem.202402601

Unlocking New Frontiers: Photo‐Isomerism and Magnetic Properties in Multifunctional Hetero‐Tetra‐Metallic Complexes

2025· article· en· W4407702268 on OpenAlexfundno aff
Ingrid Suzana, Jérémy Forté, Sébastien Pillet, El‐Eulmi Bendeif, Moritz Malischewski, Valérie Marvaud

Bibliographic record

VenueChemistry - A European Journal · 2025
Typearticle
Languageen
FieldMaterials Science
TopicMagnetism in coordination complexes
Canadian institutionsnot available
FundersGerman Academic Exchange ServiceDeutscher Akademischer AustauschdienstCentre National de la Recherche ScientifiqueProvidence Health CareAgence Nationale de la RechercheSorbonne UniversitéDeutsche Forschungsgemeinschaft
KeywordsTetraMetalMaterials scienceMagnetMoleculeMetal ions in aqueous solutionSchiff baseSingle-molecule magnetMagnetic susceptibilityRational designCombinatorial chemistryNanotechnologyChemistryCrystallographyPolymer chemistryMagnetizationMetallurgyOrganic chemistryMedicinal chemistryMagnetic fieldPhysics

Abstract

fetched live from OpenAlex

Abstract Hetero‐tetra‐metallic complexes, Fe NO CuLnCo (Ln=Gd, Tb, Dy), combining magnetic properties and photo‐isomerism, were obtained through the rational assembly of the photo‐switching nitroprusside anion Fe NO with new magnetic Schiff base CuLnCo precursors. Herein, we describe the synthesis and characterisation of these compounds followed by a demonstration of their multifunctional character. Particularly noteworthy is the Fe NO CuTbCo complex which is one of the few examples of a photo‐isomerisable SMM.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.347
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.224
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes1
Has abstractyes

Explore more

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