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Record W4407841549 · doi:10.1103/physreva.111.022813

Investigating the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mn>4</mml:mn> <mml:msub> <mml:mi>D</mml:mi> <mml:mrow> <mml:mn>3</mml:mn> <mml:mo>/</mml:mo> <mml:mn>2</mml:mn> </mml:mrow> </mml:msub> <mml:mrow> <mml:mo>|</mml:mo> <mml:mn>3</mml:mn> <mml:mo>,</mml:mo> <mml:mo>±</mml:mo> <mml:mn>2</mml:mn> <mml:mo>〉</mml:mo> </mml:mrow> </mml:mrow> </mml:math> – <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mn>4</mml:mn> <mml:msub> <mml:mi>D</mml:mi> <mml:mrow> <mml:mn>5</mml:mn> <mml:mo>/</mml:mo> <mml:mn>2</mml:mn> </mml:mrow> </mml:msub> <mml:mrow> <mml:mo>|</mml:mo> <mml:mn>3</mml:mn> <mml:mo>,</mml:mo> <mml:mo>±</mml:mo> <mml:mn>2</mml:mn> <mml:mo>〉</mml:mo> </mml:mrow> </mml:mrow> </mml:math> transition in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:msup> <mml:mrow> <mml:mi>Nb</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>4</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:math> for a THz atomic clock

2025· article· lv· W4407841549 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenuePhysical review. A/Physical review, A · 2025
Typearticle
Languagelv
FieldPhysics and Astronomy
TopicAdvanced Frequency and Time Standards
Canadian institutionsPerimeter Institute
FundersMinistry of Colleges and UniversitiesPhysical Research LaboratoryIndian Space Research OrganisationNational Natural Science Foundation of ChinaGovernment of CanadaInnovation, Science and Economic Development CanadaArthritis National Research Foundation
KeywordsChemistry

Abstract

fetched live from OpenAlex

In this work, the $4{D}_{3/2}|3,\ifmmode\pm\else\textpm\fi{}2\ensuremath{\rangle}\ensuremath{\rightarrow}4{D}_{5/2}|3,\ifmmode\pm\else\textpm\fi{}2\ensuremath{\rangle}$ transition in the ${\mathrm{Nb}}^{4+}$ ion is identified as a promising candidate for a terahertz (THz) atomic clock, with the transition frequency occurring at 56.022 4 THz. This transition is primarily driven by the magnetic dipole decay channel, which can easily be accessed by a laser. We focus on the stable $^{93}\mathrm{Nb}$ isotope, which has 100% natural abundance and a nuclear spin of $I=9/2$ for experimental advantage. Our data analysis allows us to estimate potential systematic shifts in the proposed clock system, including those due to blackbody radiation, electric quadrupole, second-order Zeeman, and second-order Doppler shifts. The scheme presented in this study can help suppress the ac Stark and electric quadrupole shifts in the clock-frequency measurement. All these analyses suggest that the proposed THz atomic clock using ${\mathrm{Nb}}^{4+}$ could be valuable in both quantum thermometry and frequency metrology.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.018
metaresearch head score (Gemma)0.016
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMetaresearch, Meta-epidemiology (narrow), Meta-epidemiology (broad), Science and technology studies, Scholarly communication, Open science, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Open science, Research integrity, Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.773
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0180.016
Meta-epidemiology (narrow)0.0120.021
Meta-epidemiology (broad)0.0050.022
Bibliometrics0.0060.015
Science and technology studies0.0150.018
Scholarly communication0.0140.015
Open science0.0230.018
Research integrity0.0190.020
Insufficient payload (model declined to judge)0.3920.018

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.271
Teacher spread0.253 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it