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Record W4407922364 · doi:10.1038/s41467-025-56970-z

Detection of ferrihydrite in Martian red dust records ancient cold and wet conditions on Mars

2025· article· en· W4407922364 on OpenAlexafffund
Adomas Valantinas, John F. Mustard, V. F. Chevrier, N. Mangold, J. L. Bishop, A. Pommerol, Pierre Beck, Olivier Poch, D. M. Applin, E. A. Cloutis, T. Hiroi, Kevin Robertson, Sebastian Pérez-López, Rafael Ottersberg, Gerónimo Villanueva, Aurélien Stcherbinine, Manish Patel, N. Thomas

Bibliographic record

VenueNature Communications · 2025
Typearticle
Languageen
FieldPhysics and Astronomy
TopicPlanetary Science and Exploration
Canadian institutionsUniversity of Winnipeg
FundersNatural Sciences and Engineering Research Council of CanadaCanadian Space AgencyCentre National d’Etudes SpatialesSchweizerischer Nationalfonds zur Förderung der Wissenschaftlichen ForschungNational Aeronautics and Space AdministrationMinistère des relations internationales et de la FrancophonieUniversity of BernResearch ManitobaNational Science Foundation
KeywordsFerrihydriteMartianMars Exploration ProgramHematiteMartian surfaceAstrobiologyAtmosphere of MarsIron oxideGeochemistryMineralogyGeologyMaterials scienceChemistryPhysics

Abstract

fetched live from OpenAlex

Abstract Iron oxide-hydroxide minerals in Martian dust provide crucial insights into Mars’ past climate and habitability. Previous studies attributed Mars’ red color to anhydrous hematite formed through recent weathering. Here, we show that poorly crystalline ferrihydrite (Fe 5 O 8 H · nH 2 O) is the dominant iron oxide-bearing phase in Martian dust, based on combined analyses of orbital, in-situ, and laboratory visible near-infrared spectra. Spectroscopic analyses indicate that a hyperfine mixture of ferrihydrite, basalt and sulfate best matches Martian dust observations. Through laboratory experiments and kinetic calculations, we demonstrate that ferrihydrite remains stable under present-day Martian conditions, preserving its poorly crystalline structure. The persistence of ferrihydrite suggests it formed during a cold, wet period on early Mars under oxidative conditions, followed by a transition to the current hyper-arid environment. This finding challenges previous models of continuous dry oxidation and indicates that ancient Mars experienced aqueous alteration before transitioning to its current desert state.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.433
Threshold uncertainty score0.228

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.270
Teacher spread0.257 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations19
Published2025
Admission routes2
Has abstractyes

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