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Record W4408234780 · doi:10.1021/acssusresmgt.4c00376

Pore-Scale Analysis of Green Solvents for Solvent-Based Bitumen Recovery

2025· article· en· W4408234780 on OpenAlexafffund
Mohammad Alikarami, Sedigheh Mahdavi, J.M. Sosa, Jinguang Hu, Arindom Sen, Hector De la Hoz Siegler

Bibliographic record

VenueACS Sustainable Resource Management · 2025
Typearticle
Languageen
FieldEngineering
TopicInnovative Microfluidic and Catalytic Techniques Innovation
Canadian institutionsUniversity of Calgary
FundersCanada First Research Excellence Fund
KeywordsAsphaltSolventScale (ratio)ChemistryChromatographyChemical engineeringEnvironmental scienceMaterials scienceOrganic chemistryEngineeringComposite materialPhysics

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Bitumen is a critical resource for materials and energy, but its high viscosity requires energy-intensive recovery methods with significant environmental impacts. While CO 2 emissions per barrel from oil sands have decreased by 30% over two decades, further innovations are needed for sustainable extraction. We studied green solvents derived from biomass as an environmentally friendly alternative to hydrocarbons in solvent-assisted bitumen recovery. Using Hansen solubility parameters, we optimized binary solvent mixtures to enhance the solubility and minimize viscosity. A novel high-pressure microfluidic device was used to simulate reservoir conditions, verify predictions based on Hansen solubility, and evaluate recovery performance, while dynamic light scattering and elemental analyses revealed the effect of solvent composition on bitumen precipitation and solubility. In toluene/furfural and toluene/guaiacol mixtures, the particle size of dispersed species was larger than that in toluene/ethyl acetate. Moreover, heptane/ethyl acetate caused a higher precipitation of the aromatic fractions. These findings advance the understanding of green solvents for reducing the carbon footprint of bitumen recovery technologies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.231
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes2
Has abstractyes

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Same venueACS Sustainable Resource ManagementSame topicInnovative Microfluidic and Catalytic Techniques InnovationFrench-language works237,207