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Record W4408280170 · doi:10.1021/acs.analchem.4c06086

Fast and Accurate Prediction of Antibiotic Susceptibility in Clinical Methicillin-Resistant <i>S. aureus</i> Isolates Using ATR-FTIR Spectroscopy: A Model Validation Study

2025· article· en· W4408280170 on OpenAlexaff
Kamila Kochan, Jhih‐Hang Jiang, Xenia Kostoulias, Elizabeth Lai, Z.J. Richardson, Savithri Pebotuwa, Philip Heraud, Bayden R. Wood, Anton Y. Peleg

Bibliographic record

VenueAnalytical Chemistry · 2025
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicSpectroscopy Techniques in Biomedical and Chemical Research
Canadian institutionsImpact
FundersNational Health and Medical Research Council
KeywordsChemistryFourier transform infrared spectroscopyAntibioticsSpectroscopyClinical microbiologyMicrobiologyBiochemistryChemical engineering

Abstract

fetched live from OpenAlex

Diagnosing antimicrobial resistance (AMR) remains critical for improving patient survival rates and treatment outcomes. Current antibiotic susceptibility tests (AST) suffer prolonged turnaround times, necessitating a minimum of 24 h for results. Attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy emerges as a promising phenotypic testing method in bacteriology due to its rapid chemical characterization capability. Here, we present an innovative approach utilizing ATR-FTIR spectroscopy for rapid AMR assessment, distinguishing between methicillin-resistant Staphylococcus aureus (MRSA) and methicillin-susceptible S. aureus (MSSA). Our approach focuses on detecting early markers of effective antibiotic action and using these to predict resistance profiles. To identify the earliest time for detection, five MSSA and five MRSA strains were subjected to oxacillin exposure for up to 2 h. We observed discernible molecular changes arising in MSSA as early as 1 h after exposure to oxacillin, which were absent in MRSA strains. Bands at 1624 and 1515 cm –1 were identified as markers of positive drug response in MSSA using principal component analysis (PCA) and were associated with peptidoglycan precursor accumulation upon transpeptidation inhibition. To develop predictive models for determining resistance profiles, we implemented ML-based modeling of the spectral data, reflective of the oxacillin-induced chemical composition changes in MSSA and MRSA. Partial least squares discriminant analysis (PLS-DA) and support vector machines classification (SVM-C) algorithms produced the best results, achieving 100% consistency with minimum inhibitory concentration (MIC) classification. Our models were independently validated by blind testing with 35 clinical strains and demonstrated 100% agreement with resistance profiling determined by MIC. Our study underscores the potential of ATR-FTIR spectroscopy for rapid and accurate AMR assessment, with the capacity to revolutionize diagnostics in combating antibiotic resistance.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Methods · Consensus signal: none
Teacher disagreement score0.011
Threshold uncertainty score0.022

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.037
GPT teacher head0.398
Teacher spread0.361 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2025
Admission routes1
Has abstractyes

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