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Record W4408343437 · doi:10.1002/advs.202416686

Wood Biomolecules as Agricultural Adjuvants for Effective Suppression of Droplet Rebound from Plant Foliage

2025· article· en· W4408343437 on OpenAlexafffund
Mamata Bhattarai, Hedar H. Al‐Terke, Kai Liu, Zhangmin Wan, Petri Kilpeläinen, Alistair W. T. King, Alexey Khakalo, Jiayun Xu, Chunlin Xu, Robin H. A. Ras, Bruno D. Mattos, Orlando J. Rojas

Bibliographic record

VenueAdvanced Science · 2025
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicPlant Surface Properties and Treatments
Canadian institutionsUniversity of British Columbia
FundersLuonnonvarakeskusCanada Excellence Research Chairs, Government of CanadaHorizon 2020 Framework ProgrammeGovernment of Canada
KeywordsLigninAgrochemicalHemicellulosePolymerCropBiomoleculeChemistryChemical engineeringMaterials scienceAgriculturePulp and paper industryNanotechnologyAgronomyOrganic chemistryBiology

Abstract

fetched live from OpenAlex

The agrochemical run-off associated with crop control is an unintended consequence of droplet rebound from plant foliage, which negatively affects crop performance and the environment. This is most critical in water-based formulations delivered on plant surfaces that are typically waxy and nonwetting. This study introduces an alternative to synthetic surfactants and high molecular weight polymers that are used as spreading agents for agrochemicals. Specifically, biopolymeric adjuvants (hemicelluloses and oligomeric lignin) extracted from wood by pressurized hot water are shown for their synergistic pinning capacity and surface activity that can effectively suppress droplet rebound from hydrophobic surfaces. Hemicellulose and lignin mixtures, alongside several model compounds, are investigated for understanding the dynamics of droplet impact and its correlation with biomacromolecule formations. The benefit of utilizing lean solutions (0.1 wt.% concentration) is highlighted for reducing droplet rebounding from leaves, outperforming synthetic systems in current use. For instance, a tenfold deposition improvement is demonstrated on citrus leaves, because of a significantly suppressed droplet roll-off. These results establish the excellent prospects of wood extracts to improve crop performance.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.130
Threshold uncertainty score0.292

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.238
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes2
Has abstractyes

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