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Record W4408485819 · doi:10.5194/egusphere-egu25-17986

Addressing uncertainties in top-down estimates of national-scale greenhouse gas emissions across different inversion systems

2025· preprint· en· W4408485819 on OpenAlexaboutno aff
Daniela Brito Melo, Alice E. Ramsden, Hélène De Longueville, Alison L. Redington, Alexandre Danjou, Peter Andrews, Brendan Murphy, Joseph Pitt, Eric Saboya, Matthew Rigby, Lukas Emmenegger, Alistair J. Manning, Stephan Henne, Anita L. Ganesan

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEnvironmental Science
TopicAtmospheric and Environmental Gas Dynamics
Canadian institutionsnot available
Fundersnot available
KeywordsGreenhouse gasInversion (geology)Environmental scienceScale (ratio)GeographyGeologySeismologyCartographyOceanography

Abstract

fetched live from OpenAlex

As part of the current international effort to limit global warming, signatories to the Paris Agreement are required to quantify their greenhouse gas (GHG) emissions. Former Kyoto Annex I countries thus report their emissions annually to the United Nations Framework Convention on Climate Change (UNFCCC) . This assessment allows countries to evaluate their progress in reducing GHG emissions and their compliance with existing agreements.The general approach to quantifying GHG emissions at the national level is to use activity data and emission factors (bottom-up method). An independent quantification can be achieved with inverse modelling, which makes use of an a priori estimate, atmospheric transport models (ATM), and atmospheric measurements of GHG concentrations (top-down method). However, the accuracy and uncertainty of inverse estimates are highly dependent on several parameters and modelling choices. Consequently, inter-model variability can be significant, potentially limiting the use of this technique in policy-relevant discussions.A representative quantification of GHG emissions based on inverse modelling requires an in-depth understanding of different inverse model estimates, their uncertainties and model limitations. An intercomparison of three inverse methods and a suite of sensitivity tests were performed. This exercise considered two fluorinated gases (HFC-143a and PFC-218), which are potent GHGs with very different emission characteristics (diffuse versus point source). Both are covered under the European F-gas regulation. Additionally, HFC-143a is expected to be phased-down under the Kigali Amendment to the Montreal Protocol.We found that top-down estimates for Central and Western European countries are most sensitive to the ATM used. For gases with localised emission sources, such as PFC-218, the choice of a priori emissions and assigned model-data mismatch uncertainty are particularly relevant. For gases with widely distributed emission sources, such as HFC-143a, the emission estimates are more consistent and less sensitive to modelling choices. This detailed understanding of uncertainties in top-down estimates is then used to inform how inverse modelling can be used to support the reporting of halogenated GHG emissions at the national and European level.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.008
metaresearch head score (Gemma)0.017
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.016
Threshold uncertainty score0.044

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0080.017
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0020.002
Open science0.0010.002
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.280
Teacher spread0.255 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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