Novel statistical analysis illustrates the importance of flow source for extreme variation in dissolved organic carbon in a eutrophic reservoir in the Great Plains
Bibliographic record
Abstract
Dissolved organic carbon (DOC) trends, predominantly showing long-term increases in concentration, have been observed across many regions of the Northern Hemisphere. Elevated DOC concentrations are a major concern for drinking water treatment plants, owing to the effects of disinfection byproduct formation, the risk of bacterial regrowth in water distribution systems, and treatment cost increases. Using a unique 30-year data set encompassing both extreme wet and dry conditions in a eutrophic drinking water reservoir in the Great Plains of North America, we investigate the effects of changing source-water and in-lake water chemistry on DOC. We employ novel wavelet coherence analyses to explore the coherence of changes in DOC with other environmental variables and apply a generalized additive model to understand predictor–DOC responses. We found that the DOC concentration was significantly coherent with (and lagging behind) flow from a large upstream mesotrophic reservoir at long ( > 18-month) timescales. DOC was also coherent with (lagging behind) sulfate and in phase with total phosphorus, ammonium, and chlorophyll a concentrations at short (≤ 18-month) timescales across the 30-year record. These variables accounted for 56 % of the deviance in DOC from 1990 to 2019, suggesting that water-source and in-lake nutrient and solute chemistry are effective predictors of the DOC concentration. Clearly, climate and changes in water and catchment management will influence source-water quality in this already water-scarce region. Our results highlight the importance of flow management to shallow eutrophic reservoirs; wet periods can exacerbate water quality issues, and these effects can be compounded by reducing inflows from systems with lower DOC. These flow management decisions address water level and flood risk concerns but also have important impacts on drinking water treatability.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".